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Stereoselective Synthesis of Functionalized Pyrrolidines via a [3 + 2]-Annulation of N-Ts-α-Amino Aldehydes and 1,3-Bis(silyl)propenes

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Per Restorp,^† Andreas Fischer,^‡ and Peter Somfai*^†

Organic Chemistry and Inorganic Chemistry, KTH Chemical Science and Engineering, 100 44 Stockholm, Sweden

J. Am. Chem. Soc., 2006, 128 (39), pp 12646–12647

DOI: 10.1021/ja0647102

Publication Date (Web): September 9, 2006

†

Organic Chemistry.

‡

Inorganic Chemistry.

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, somfai@kth.se

Abstract

An efficient protocol for stereoselective synthesis of densely functionalized pyrrolidines by a [3 + 2]-annulation of N-Ts-α-amino aldehydes and 1,3-bis(silyl)propenes is described.

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Published In Issue October 04, 2006
Received July 12, 2006

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Communication

Stereoselective Synthesis of Functionalized Pyrrolidines via a [3 + 2]-Annulation of N-Ts-α-Amino Aldehydes and 1,3-Bis(silyl)propenes

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Consecutive Intramolecular Hydroamination/Asymmetric Transfer Hydrogenation under Relay Catalysis of an Achiral Gold Complex/Chiral Brønsted Acid Binary System

Target-Directed Organocatalysis: A Direct Asymmetric Catalytic Approach to Chiral Propargylic and Allylic Fluorides

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