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Article

Photosensitive Function of Encapsulated Dye in Carbon Nanotubes

Supporting Info

Kazuhiro Yanagi,*^† Konstantin Iakoubovskii,^† Hiroyuki Matsui,^‡ Hiroyuki Matsuzaki,^‡ Hiroshi Okamoto,^‡ Yasumitsu Miyata,^§ Yutaka Maniwa,^§ Said Kazaoui,^† Nobutsugu Minami,^† and Hiromichi Kataura^†

Contribution from the National Institute of Advanced Industrial Science and Technology (AIST), Ibaraki 305-8562, Japan, Department of Advanced Materials Science, The University of Tokyo, Chiba 277-8561, Japan, and Department of Physics, Tokyo Metropolitan University, Tokyo 192-0397, Japan

J. Am. Chem. Soc., 2007, 129 (16), pp 4992–4997

DOI: 10.1021/ja067351j

Publication Date (Web): April 3, 2007

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

†

AIST.

‡

The University of Tokyo.

Tokyo Metropolitan University.

, k-yanagi@aist.go.jp

Abstract

Single-wall carbon nanotubes (SWCNTs) exhibit resonant absorption localized in specific spectral regions. To expand the light spectrum that can be utilized by SWCNTs, we have encapsulated squarylium dye into SWCNTs and clarified its microscopic structure and photosensitizing function. X-ray diffraction and polarization-resolved optical absorption measurements revealed that the encapsulated dye molecules are located at an off center position inside the tubes and aligned to the nanotube axis. Efficient energy transfer from the encapsulated dye to SWCNTs was clearly observed in the photoluminescence spectra. Enhancement of transient absorption saturation in the S1 state of the semiconducting SWCNTs was detected after the photoexcitation of the encapsulated dye, which indicates that ultrafast (<190 fs) energy transfer occurred from the dye to the SWCNTs.

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