Cart
Communication
Fe(salan)-Catalyzed Asymmetric Oxidation of Sulfides with Hydrogen Peroxide in Water
Full Text HTML
Hi-Res PDFPurchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
A new chiral Fe(salan) complex was synthesized, and it was found to serve as an efficient catalyst for asymmetric oxidation of sulfides using hydrogen peroxide in water without surfactant. Not only alkyl aryl sulfides but also various methyl alkyl sulfides were oxidized to the corresponding sulfoxides with high enantioselectivities up to 96% ee. It should be noted that the turnover number of complex 4 amounts to 8000.
Citing Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 15 ACS Journal articles (5 most recent appear below).
Direct C−H Transformation via Iron Catalysis
Chang-Liang Sun, Bi-Jie Li, and Zhang-Jie ShiChemical Reviews2011 111 (3), 1293-1314Direct C−H Transformation via Iron Catalysis
Chang-Liang Sun, Bi-Jie Li, and Zhang-Jie ShiChemical Reviews2011 111 (3), 1293-1314
Ultrasound-Promoted Oxidation of Sulfides with Hydrogen Peroxide under Catalyst-Free Conditions
Praveen K. Khatri, Suman L. Jain, and Bir SainIndustrial & Engineering Chemistry Research2011 50 (2), 701-704Ultrasound-Promoted Oxidation of Sulfides with Hydrogen Peroxide under Catalyst-Free Conditions
Praveen K. Khatri, Suman L. Jain, and Bir SainIndustrial & Engineering Chemistry Research2011 50 (2), 701-704Ultrasonication is an advanced approach toward achieving the aim of green chemical synthesis. In this Article, we have described the unique effect of the ultrasound in the oxidation of sulfides to sulfoxides with high selectivities without any catalyst by ...
Catalytic Asymmetric Oxidation of Cyclic Dithioacetals: Highly Diastereo- and Enantioselective Synthesis of the S-Oxides by a Chiral Aluminum(salalen) Complex
Junichi Fujisaki, Kenji Matsumoto, Kazuhiro Matsumoto, and Tsutomu KatsukiJournal of the American Chemical Society2011 133 (1), 56-61Catalytic Asymmetric Oxidation of Cyclic Dithioacetals: Highly Diastereo- and Enantioselective Synthesis of the S-Oxides by a Chiral Aluminum(salalen) Complex
Junichi Fujisaki, Kenji Matsumoto, Kazuhiro Matsumoto, and Tsutomu KatsukiJournal of the American Chemical Society2011 133 (1), 56-61Aluminum(salalen) complex 1 [salalen = half-reduced salen, salen = N,N′-ethylenebis(salicylideneiminato)] was found to be a highly efficient catalyst for asymmetric oxidation of cyclic dithioacetals in the presence of 30% hydrogen peroxide as an oxidant. ...
Iron(II) Complexes with Tetradentate Bis(aminophenolate) Ligands: Synthesis and Characterization, Solution Behavior, and Reactivity with O2
Christopher J. Whiteoak, Rafael Torres Martin de Rosales, Andrew J. P. White, and George J. P. BritovsekInorganic Chemistry2010 49 (23), 11106-11117Iron(II) Complexes with Tetradentate Bis(aminophenolate) Ligands: Synthesis and Characterization, Solution Behavior, and Reactivity with O2
Christopher J. Whiteoak, Rafael Torres Martin de Rosales, Andrew J. P. White, and George J. P. BritovsekInorganic Chemistry2010 49 (23), 11106-11117Tetradentate bis(aminophenolate) ligands H2salanX and H2bapenX (where X refers to the para-phenolate substituent = H, Me, F, Cl) react with [Fe{N(SiMe3)2}2] to form iron(II) complexes, which in the presence of suitable donor ligands L (L = pyridine or THF)...
Photopromoted Ru-Catalyzed Asymmetric Aerobic Sulfide Oxidation and Epoxidation Using Water as a Proton Transfer Mediator
Haruna Tanaka, Hiroaki Nishikawa, Tatsuya Uchida and Tsutomu KatsukiJournal of the American Chemical Society2010 132 (34), 12034-12041Photopromoted Ru-Catalyzed Asymmetric Aerobic Sulfide Oxidation and Epoxidation Using Water as a Proton Transfer Mediator
Haruna Tanaka, Hiroaki Nishikawa, Tatsuya Uchida and Tsutomu KatsukiJournal of the American Chemical Society2010 132 (34), 12034-12041Ru(NO)−salen complexes were found to catalyze asymmetric aerobic oxygen atom transfer reactions such as sulfide oxidation and epoxidation in the presence of water under visible light irradiation at room temperature. Oxidation of sulfides including alkyl ...
Tools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Published In Issue July 25, 2007
- Received March 19, 2007
ACS
Network
Facebook
Tweet This
CiteULike
Newsvine
Digg This
Delicious
