BaGe₅: A New Type of Intermetallic Clathrate

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Abstract

BaGe₅ constitutes a new type of intermetallic clathrate obtained by decomposition of clathrate-I Ba₈Ge₄₃₃ at low temperatures. The crystal structure consists of characteristic layers interconnected by covalent bonds. BaGe₅ is a semiconducting Zintl phase.

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This article has been cited by 5 ACS Journal articles (5 most recent appear below).

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  High-Pressure Synthesis and Superconductivity of a New Binary Barium Germanide BaGe₃

  Hiroshi Fukuoka, Yusuke Tomomitsu, and Kei Inumaru
  Inorganic Chemistry2011 Article ASAP

  • High-Pressure Synthesis and Superconductivity of a New Binary Barium Germanide BaGe₃

    Hiroshi Fukuoka, Yusuke Tomomitsu, and Kei Inumaru
    Inorganic Chemistry2011 Article ASAP

    A new binary barium germanide BaGe3 was prepared by high-pressure and high-temperature reactions using a Kawai type multi-anvil press. It crystallizes in a hexagonal unit cell with a = 6.814(1) Å, c = 5.027(8) Å, and V = 202.2(5) Å3 (the space group P63/...

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• 

  High-Pressure Synthesis and Superconductivity of a New Binary Lanthanum Germanide LaGe₃ with Triangular Ge₃ Cluster Units

  Hiroshi Fukuoka, Koichiro Suekuni, Takahiro Onimaru, and Kei Inumaru
  Inorganic Chemistry2011 50 (9), 3901-3906

  • High-Pressure Synthesis and Superconductivity of a New Binary Lanthanum Germanide LaGe₃ with Triangular Ge₃ Cluster Units

    Hiroshi Fukuoka, Koichiro Suekuni, Takahiro Onimaru, and Kei Inumaru
    Inorganic Chemistry2011 50 (9), 3901-3906

    We prepared a new binary lanthanum germanide, LaGe3, under high-pressure and high-temperature conditions (3−12 GPa, 500−1200 °C). It crystallizes in the BaPb3 structure (the space group R3̅m) with lattice constants of a = 6.376(1) Å, c = 22.272(3) Å, and ...

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• 

  Synthesis of the Clathrate-I Phase Ba_8−xSi₄₆ via Redox Reactions

  Ying Liang, Bodo Böhme, Marianne Reibold, Walter Schnelle, Ulrich Schwarz, Michael Baitinger, Hannes Lichte, and Yuri Grin
  Inorganic Chemistry2011 Article ASAP

  • Synthesis of the Clathrate-I Phase Ba_8−xSi₄₆ via Redox Reactions

    Ying Liang, Bodo Böhme, Marianne Reibold, Walter Schnelle, Ulrich Schwarz, Michael Baitinger, Hannes Lichte, and Yuri Grin
    Inorganic Chemistry2011 Article ASAP

    The clathrate-I phase Ba8−xSi46 (space group Pm3̅n) was synthesized by oxidation of Ba4Li2Si6 with gaseous HCl. Microcrystalline powders of the clathrate phase were obtained within a few minutes. The reaction temperature and the pressure of HCl were ...

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• 

  Structural Principles of Semiconducting Group 14 Clathrate Frameworks

  Antti J. Karttunen, Thomas F. Fässler, Mikko Linnolahti, and Tapani A. Pakkanen
  Inorganic Chemistry2011 50 (5), 1733-1742

  • Structural Principles of Semiconducting Group 14 Clathrate Frameworks

    Antti J. Karttunen, Thomas F. Fässler, Mikko Linnolahti, and Tapani A. Pakkanen
    Inorganic Chemistry2011 50 (5), 1733-1742

    We have performed a comprehensive theoretical investigation of the structural principles of semiconducting clathrate frameworks composed of the Group 14 elements carbon, silicon, germanium, and tin. We have investigated the basic clathrate frameworks, ...

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• 

  Atomic Interactions in the p-Type Clathrate I Ba₈Au_5.3Ge_40.7

  Hui Zhang, Horst Borrmann, Niels Oeschler, Christophe Candolfi, Walter Schnelle, Marcus Schmidt, Ulrich Burkhardt, Michael Baitinger, Jing-Tai Zhao, and Yuri Grin
  Inorganic Chemistry2011 50 (4), 1250-1257

  • Atomic Interactions in the p-Type Clathrate I Ba₈Au_5.3Ge_40.7

    Hui Zhang, Horst Borrmann, Niels Oeschler, Christophe Candolfi, Walter Schnelle, Marcus Schmidt, Ulrich Burkhardt, Michael Baitinger, Jing-Tai Zhao, and Yuri Grin
    Inorganic Chemistry2011 50 (4), 1250-1257

    Single crystals of Ba8Au5.3Ge40.7 [space group Pm3̅n (No. 223), a = 10.79891(8) Å] were prepared by a Bridgman technique. The crystal structure refinement based on single-crystal X-ray diffraction data does not reveal any vacancies in the Au/Ge framework ...

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