Cart
Communication
Catalytic Asymmetric Epoxidation of Cyclic Enones
Full Text HTML
Hi-Res PDFPurchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
A highly enantioselective epoxidation of cyclic enones with hydrogen peroxide has been developed that is catalyzed by chiral primary amine salts.
Citing Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 22 ACS Journal articles (5 most recent appear below).
Theoretical Investigation on the Chiral Diamine-Catalyzed Epoxidation of Cyclic Enones: Mechanism and Effects of Cocatalyst
Ping-Li Lv, Rong-Xiu Zhu, Dong-Ju Zhang, Chong-Gang Duan, and Cheng-Bu LiuThe Journal of Physical Chemistry A2012 116 (4), 1251-1260Theoretical Investigation on the Chiral Diamine-Catalyzed Epoxidation of Cyclic Enones: Mechanism and Effects of Cocatalyst
Ping-Li Lv, Rong-Xiu Zhu, Dong-Ju Zhang, Chong-Gang Duan, and Cheng-Bu LiuThe Journal of Physical Chemistry A2012 116 (4), 1251-1260The asymmetric epoxidation of 2-cyclohexen-1-one with aqueous H2O2 as oxidant, 1,2-diaminocyclohexane as catalyst, and a Brønsted acid trifluoroacetic acid (TFA) as cocatalyst has been studied by performing density functional theory calculations. It is ...
Organocatalytic Asymmetric Michael-Type/Wittig Reaction of Phosphorus Ylides: Synthesis of Chiral α-Methylene-δ-Ketoesters
Aijun Lin, Junying Wang, Haibin Mao, Huiming Ge, Renxiang Tan, Chengjian Zhu, and Yixiang ChengOrganic Letters2011 Article ASAPOrganocatalytic Asymmetric Michael-Type/Wittig Reaction of Phosphorus Ylides: Synthesis of Chiral α-Methylene-δ-Ketoesters
Aijun Lin, Junying Wang, Haibin Mao, Huiming Ge, Renxiang Tan, Chengjian Zhu, and Yixiang ChengOrganic Letters2011 Article ASAPAn asymmetric Michael-type reaction of phosphorus ylides and α,β-unsaturated ketones under the catalysis of a chiral ion pair catalyst has been described. The ion pair catalyst containing a chiral counteranion was prepared by simply mixing 9-amino-(9-...
Effect of High Pressure on the Organocatalytic Asymmetric Michael Reaction: Highly Enantioselective Synthesis of γ-Nitroketones with Quaternary Stereogenic Centers
Piotr Kwiatkowski, Krzysztof Dudziński, and Dawid ŁyżwaOrganic Letters2011 Article ASAPEffect of High Pressure on the Organocatalytic Asymmetric Michael Reaction: Highly Enantioselective Synthesis of γ-Nitroketones with Quaternary Stereogenic Centers
Piotr Kwiatkowski, Krzysztof Dudziński, and Dawid ŁyżwaOrganic Letters2011 Article ASAPThe significant effect of hydrostatic pressure on the difficult organocatalytic 1,4-conjugate addition of nitroalkanes to prochiral sterically congested β,β-disubstituted enones is demonstrated. This approach allows for the synthesis of γ-nitroketones ...
Iron-Catalyzed Asymmetric Epoxidation of β,β-Disubstituted Enones
YASUHIRO NISHIKAWA and Hisashi YamamotoJournal of the American Chemical Society 0 (ja),Iron-Catalyzed Asymmetric Epoxidation of β,β-Disubstituted Enones
YASUHIRO NISHIKAWA and Hisashi YamamotoJournal of the American Chemical Society 0 (ja),The combination of Fe(OTf)2 and novel phenanthroline ligands enables the catalytic asymmetric epoxidation of acyclic β,β-disubstituted enones which have been heretofore inaccessible substrate classes. The reactions provide highly enantioenriched α,β-...
Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones
Piotr Kwiatkowski, Teresa D. Beeson, Jay C. Conrad, and David W. C. MacMillanJournal of the American Chemical Society2011 133 (6), 1738-1741Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones
Piotr Kwiatkowski, Teresa D. Beeson, Jay C. Conrad, and David W. C. MacMillanJournal of the American Chemical Society2011 133 (6), 1738-1741The first highly enantioselective α-fluorination of ketones using organocatalysis has been accomplished. The long-standing problem of enantioselective ketone α-fluorination via enamine activation has been overcome via high-throughput evaluation of a new ...
Tools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Published In Issue May 14, 2008
- Article ASAPApril 19, 2008
- Received: February 17, 2008
ACS
Network
Facebook
Tweet This
CiteULike
Newsvine
Digg This
Delicious
