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Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows
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Section:Abstract
Reactions between two novel hexatopic carboxylate ligands and copper salts give rise to two isostructural metal−organic frameworks (MOFs) with a (3,24)-connected network topology containing both micro- and mesocavities with sizes of up to 3 nm. Both frameworks retain their porosity after guest-molecule removal, leading to high surface areas. Constructing MOFs containing mesocavities with microwindows may serve as a general approach toward stable MOFs with high surface areas.
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This article has been cited by 28 ACS Journal articles (5 most recent appear below).
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History
- Published In Issue July 08, 2009
- Article ASAPJune 16, 2009
- Received: February 12, 2009
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