An Antibody-Catalyzed Selenoxide Elimination

Zhaohui S. Zhou, Ning Jiang, and Donald Hilvert*
Departments of Chemistry and Molecular Biology The Skaggs Institute of Chemical Biology The Scripps Research Institute 10550 North Torrey Pines Road La Jolla, California 92037
J. Am. Chem. Soc., 1997, 119 (15), pp 3623–3624
DOI: 10.1021/ja963748j
Publication Date (Web): April 16, 1997
Copyright © 1997 American Chemical Society

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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

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    An Antibody-Catalyzed Allylic Sulfoxide−Sulfenate Rearrangement

    Zhaohui S. Zhou, Alexander Flohr, and Donald Hilvert
    The Journal of Organic Chemistry1999 64 (22), 8334-8341
    • An Antibody-Catalyzed Allylic Sulfoxide−Sulfenate Rearrangement

      Zhaohui S. Zhou, Alexander Flohr, and Donald Hilvert
      The Journal of Organic Chemistry1999 64 (22), 8334-8341

      Antibodies SZ-cis-39C11 and SZ-trans-28F8, which were elicited in response to N-aryl-3-methoxyphenyl proline derivatives, catalyze the [2,3]-sigmatropic rearrangement of allylic sulfoxides to sulfenates. Reduction of the sulfenates with dithiothreitol in ...

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History

  • Published In Issue April 16, 1997
  • Received October 28, 1996

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