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Synthesis and Isolation of Stable Hypervalent Carbon Compound (10-C-5) Bearing a 1,8-Dimethoxyanthracene Ligand

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Kin-ya Akiba,*^† Makoto Yamashita,^† Yohsuke Yamamoto,^† and Shigeru Nagase^‡

Department of Chemistry, Graduate School of Science Hiroshima University, 1-3-1 Kagamiyama Higashi-Hiroshima 739-8526, Japan Department of Chemistry, Graduate School of Science Tokyo Metropolitan University, 1-1 Minami-osawa Hachioji, Tokyo 192-0397, Japan

J. Am. Chem. Soc., 1999, 121 (45), pp 10644–10645

DOI: 10.1021/ja992719g

Publication Date (Web): October 30, 1999

Section:

Benzene, Its Derivatives, and Condensed Benzenoid Compounds

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This article has been cited by 19 ACS Journal articles (5 most recent appear below).

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A Hypervalent Pentacoordinate Boron Compound with an N−B−N Three-Center Four-Electron Bond
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Stereogenic Motif Consisting of Rigid Ring and Intraannular Chains: Isolation and Structures of Stereoisomers of 9-Alkyl-1,8-anthrylene−Butadiynylene Cyclic Dimers
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  Stereoisomers of the title π-conjugated compounds with intraannular propyl and butyl groups were isolated by chromatography. The high barrier to isomerization is attributed to the steric hindrance between the alkyl chains and the rigid framework.
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Octacoordinate Carbons Encaged Inside Carborane Clusters: A Density Functional Theory Investigation
Yang Wang, Yuanhe Huang, Bing Yin, Baohua Yang and Ruozhuang Liu
The Journal of Physical Chemistry A2008 112 (33), 7643-7651
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  This work focuses on the computational design and characterization of a novel series of endohedral carborane clusters containing octacoordinate carbon centers. The structural and bonding features and the thermodynamic and kinetic stabilities are discussed ...
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