Solubility of Lead(II) Oxide and Copper(II) Oxide in Subcritical and Supercritical Water

Kiwamu Sue, Yukiya Hakuta, Richard L. Smith, Jr., Tadafumi Adschiri, and Kunio Arai*
Tohoku University, Department of Chemical Engineering, Aoba-ku, Aramaki-Aza, Aoba-07, Sendai 980-8579, Japan
J. Chem. Eng. Data, 1999, 44 (6), pp 1422–1426
DOI: 10.1021/je9901029
Publication Date (Web): November 11, 1999
Copyright © 1999 American Chemical Society

Abstract

The solubilities of lead oxide (PbO) and copper oxide (CuO) in subcritical and supercritical water were measured at temperatures from 250 °C to 500 °C and pressures from 26 MPa to 34 MPa, in a flow-type apparatus. The solubility of lead oxide varied from 351 μmol/kg H2O at 424.9 °C and 25.9 MPa to 4406 μmol/kg H2O at 350.3 °C and 30.2 MPa. The solubility of copper oxide varied from 1.3 μmol/kg H2O at 449.8 °C and 28.0 MPa to 8.0 μmol/kg H2O at 324.9 °C and 28.1 MPa. A hydration reaction model was applied to correlate the data.

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History

  • Published In Issue November 11, 1999
  • Received for review April 12, 1999. Accepted September 14, 1999.

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