Article
Solubility of Lead(II) Oxide and Copper(II) Oxide in Subcritical and Supercritical Water
Purchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Abstract
The solubilities of lead oxide (PbO) and copper oxide (CuO) in subcritical and supercritical water were measured at temperatures from 250 °C to 500 °C and pressures from 26 MPa to 34 MPa, in a flow-type apparatus. The solubility of lead oxide varied from 351 μmol/kg H2O at 424.9 °C and 25.9 MPa to 4406 μmol/kg H2O at 350.3 °C and 30.2 MPa. The solubility of copper oxide varied from 1.3 μmol/kg H2O at 449.8 °C and 28.0 MPa to 8.0 μmol/kg H2O at 324.9 °C and 28.1 MPa. A hydration reaction model was applied to correlate the data.
Citing Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
This article has been cited by 5 ACS Journal articles (5 most recent appear below).

Nonthermal Synthesis of Three-Dimensional Metal Oxide Structures under Continuous-Flow Conditions and Their Catalytic Applications
Cecil K. King’ondu, Naftali N. Opembe, Homer C. Genuino, Hector F. Garces, Eric C. Njagi, Aparna Iyer, Hui Huang, Saminda Dharmarathna, and Steven L. SuibThe Journal of Physical Chemistry C2011 115 (47), 23273-23282Nonthermal Synthesis of Three-Dimensional Metal Oxide Structures under Continuous-Flow Conditions and Their Catalytic Applications
Cecil K. King’ondu, Naftali N. Opembe, Homer C. Genuino, Hector F. Garces, Eric C. Njagi, Aparna Iyer, Hui Huang, Saminda Dharmarathna, and Steven L. SuibThe Journal of Physical Chemistry C2011 115 (47), 23273-23282Continuous-flow synthesis of one-dimensional (1D) metal oxide nanostructures and/or their integration into hierarchical structures under nonthermal conditions is still a challenge. In this work, a nonthermal, continuous-flow approach for the preparation ...

Solubility of 1:1 Alkali Nitrates and Chlorides in Near-Critical and Supercritical Water
Ingo Leusbrock, Sybrand J. Metz, Glenn Rexwinkel and Geert F. VersteegJournal of Chemical & Engineering Data2009 54 (12), 3215-3223Solubility of 1:1 Alkali Nitrates and Chlorides in Near-Critical and Supercritical Water
Ingo Leusbrock, Sybrand J. Metz, Glenn Rexwinkel and Geert F. VersteegJournal of Chemical & Engineering Data2009 54 (12), 3215-3223To increase the available data on systems containing supercritical water and inorganic compounds, an experimental setup was designed to investigate the solubilities of inorganic compounds in supercritical water. In this work, three alkali chloride salts (...

Quinacridone Solubility in Hot-Compressed Water
Kiwamu Sue, Toshihiko Usami, Kunio Arai, Hitoshi Kasai, Hachiro Nakanishi, and Toshihiko HiakiJournal of Chemical & Engineering Data2007 52 (3), 714-717Quinacridone Solubility in Hot-Compressed Water
Kiwamu Sue, Toshihiko Usami, Kunio Arai, Hitoshi Kasai, Hachiro Nakanishi, and Toshihiko HiakiJournal of Chemical & Engineering Data2007 52 (3), 714-717The solubility of quinacridone in hot-compressed water was measured for the first time at temperatures from (453.4 to 592.9) K and at a pressure of 24 MPa with a flow-type apparatus. The solubility varied from 1.07 × 10-5 mol·kg-1 at 453.4 K to 5.89 × 10-...

Continuous Production of Nickel Fine Particles by Hydrogen Reduction in Near-Critical Water
Kiwamu Sue, Nobuyoshi Kakinuma, Tadafumi Adschiri, and Kunio AraiIndustrial & Engineering Chemistry Research2004 43 (9), 2073-2078Continuous Production of Nickel Fine Particles by Hydrogen Reduction in Near-Critical Water
Kiwamu Sue, Nobuyoshi Kakinuma, Tadafumi Adschiri, and Kunio AraiIndustrial & Engineering Chemistry Research2004 43 (9), 2073-2078Nickel fine particles with diameters under 600 nm were synthesized rapidly and continuously in water at temperatures ranging from 300 to 380 °C and at 30 MPa. Nickel particles formed through the following two steps: formation of Fe3O4 nuclei by ...

Hydrothermal Synthesis of Metal Oxide Fine Particles at Supercritical Conditions
Tadafumi Adschiri, Yukiya Hakuta, and Kunio AraiIndustrial & Engineering Chemistry Research2000 39 (12), 4901-4907Hydrothermal Synthesis of Metal Oxide Fine Particles at Supercritical Conditions
Tadafumi Adschiri, Yukiya Hakuta, and Kunio AraiIndustrial & Engineering Chemistry Research2000 39 (12), 4901-4907Supercritical water can provide an excellent reaction environment for hydrothermal crystallization of metal oxide particles. Because of the drastic change of properties of water around the critical point, density, dielectric constant, and ionic product, ...
Tools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Published In Issue November 11, 1999
- Received for review April 12, 1999. Accepted September 14, 1999.
Cart

ACS
Network






