Long-Term Stability of Thujone, Fenchone, and Pinocamphone in Vintage Preban Absinthe

Dirk W. Lachenmeier*, David Nathan-Maister, Theodore A. Breaux§ and Thomas Kuballa
Chemisches und Veterinäruntersuchungsamt (CVUA) Karlsruhe, Weissenburger Strasse 3, D-76187 Karlsruhe, Germany; Oxygenee Ltd., 22 Baylis Crescent, Burgess Hill RH15 8UP, United Kingdom; and Jade Liqueurs, L.L.C., 3588 Brookfield Road, Birmingham, Alabama 35226
J. Agric. Food Chem., 2009, 57 (7), pp 2782–2785
DOI: 10.1021/jf803975m
Publication Date (Web): March 3, 2009
Copyright © 2009 American Chemical Society
* Corresponding author (telephone +49-721-926-5434; fax +49-721-926-5539; e-mail Lachenmeier@web.de)., †

CVUA Karlsruhe.

, ‡

Oxygenee Ltd.

, §

Jade Liqueurs, L.L.C.

Abstract

Abstract Image

Research was conducted to ascertain whether analyses of vintage absinthe samples represent their original composition in the early 1900s. Absinthe stored in traditional green glass bottles and irradiated with ultraviolet light for up to 200 h exhibited unchanged composition. Samples stored in clear glass exhibited an 18% reduction in β-thujone content and a concurrent decoloration. These experiments indicate the stability of thujone in vintage absinthes, as these were stored in green glass bottles. The preserved color of the preban absinthes subjected to analysis indicates that no significant light exposure occurred throughout the duration of storage, and therefore provides indirect proof that no loss of terpenes occurred. The stability of absinthe was further demonstrated through the reanalysis of samples from 2001−2005, which exhibited no changes in thujone content as of 2008. A previous evaluation of preban absinthe was therefore valid and not confounded by significant thujone deterioration over time.

Keywords:

Alcoholic beverages; absinthe; thujone; fenchone; pinocamphone; Artemisia absinthium L.; wormwood; UV irradiation; long-term storage; accelerated aging

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History

  • Published In Issue April 08, 2009
  • Article ASAPMarch 03, 2009
  • Received: December 22, 2008
    Accepted: February 10, 2009
    Revised: February 10, 2009

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