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Structure and Asymmetry in the Isomeric Conversion of β- to α-Endosulfan
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Section:Abstract
Keywords: α- and β-endosulfan; conformation; X-ray crystallography; intramolecular conversion; NMR spectroscopy
Citing Articles
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This article has been cited by 6 ACS Journal articles (5 most recent appear below).
Monitoring and Modeling Endosulfan in Chinese Surface Soil
Hongliang Jia, Liyan Liu, Yeqing Sun, Bing Sun, Degao Wang, Yushan Su, Kurunthachalam Kannan, and Yi-Fan LiEnvironmental Science & Technology2010 44 (24), 9279-9284Monitoring and Modeling Endosulfan in Chinese Surface Soil
Hongliang Jia, Liyan Liu, Yeqing Sun, Bing Sun, Degao Wang, Yushan Su, Kurunthachalam Kannan, and Yi-Fan LiEnvironmental Science & Technology2010 44 (24), 9279-9284Endosulfan is a currently used organochlorine pesticide in China, with annual usage of 2300 t between 1994 and 2004. Concentrations of endosulfan (including α- and β-isomers and their metabolite endosulfan sulfate) were reported for surface soil collected ...
Occurrence and Distribution of Organochlorine Pesticides (OCPs) in Tomato (Lycopersicon esculentum) Crops from Organic Production
Mariana Gonzalez, Karina S. B. Miglioranza, Julia E. Aizpún de Moreno, and Víctor J. MorenoJournal of Agricultural and Food Chemistry2003 51 (5), 1353-1359Occurrence and Distribution of Organochlorine Pesticides (OCPs) in Tomato (Lycopersicon esculentum) Crops from Organic Production
Mariana Gonzalez, Karina S. B. Miglioranza, Julia E. Aizpún de Moreno, and Víctor J. MorenoJournal of Agricultural and Food Chemistry2003 51 (5), 1353-1359Organochlorine pesticides (OCPs) were quantified by GC-ECD in tomato (Lycopersicon esculentum) during a vegetation period. Plants were harvested at 15, 60, and 151 days after seed germination. Leaves, stem, roots, and fruit (peel and flesh) were analyzed ...
Surface-Catalyzed Transformations of Aqueous Endosulfan
Spencer S. Walse, Ken D. Shimizu, and John L. FerryEnvironmental Science & Technology2002 36 (22), 4846-4853Surface-Catalyzed Transformations of Aqueous Endosulfan
Spencer S. Walse, Ken D. Shimizu, and John L. FerryEnvironmental Science & Technology2002 36 (22), 4846-4853We report the effect of suspended solids on the oxidation and hydrolysis of the insecticide endosulfan (α and β isomers) and its degradation products: endosulfan diol, endosulfan sulfate, endosulfan ether, and endosulfan lactone in 0.001 M NaHCO3 buffer (...
Herbicide and Insecticide Loadings from the Susquehanna River to the Northern Chesapeake Bay
Bo Liu, Laura L. McConnell, and Alba TorrentsJournal of Agricultural and Food Chemistry2002 50 (15), 4385-4392Herbicide and Insecticide Loadings from the Susquehanna River to the Northern Chesapeake Bay
Bo Liu, Laura L. McConnell, and Alba TorrentsJournal of Agricultural and Food Chemistry2002 50 (15), 4385-4392The Susquehanna River watershed has a large drainage area (71200 km2) containing heavy agricultural land usage. The river provides approximately half the total freshwater input to the Chesapeake Bay. Water samples were collected at Conowingo Dam near the ...
Thermodynamic, Spectroscopic, and Computational Evidence for the Irreversible Conversion of β- to α-Endosulfan
Walter F. Schmidt, Susanna Bilboulian, Clifford P. Rice, James C. Fettinger, Laura L. McConnell, and Cathleen J. HapemanJournal of Agricultural and Food Chemistry2001 49 (11), 5372-5376Thermodynamic, Spectroscopic, and Computational Evidence for the Irreversible Conversion of β- to α-Endosulfan
Walter F. Schmidt, Susanna Bilboulian, Clifford P. Rice, James C. Fettinger, Laura L. McConnell, and Cathleen J. HapemanJournal of Agricultural and Food Chemistry2001 49 (11), 5372-5376Previous studies have provided unequivocal evidence for the symmetry of β-endosulfan and the corresponding asymmetry of α-endosulfan; the conversion of β-endosulfan to α-endosulfan was identified. In this study, evidence from differential scanning ...
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- Published In Issue April 16, 1997
- Received for review January 7, 1997. Accepted January 29, 1997. Mention of specific products or suppliers is for identification and does not imply endorsement by the U.S. Depart ment of Agriculture to the exclusion of other suitable products or suppliers.
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