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Scope and stereochemical course of the addition of (trimethylsilyl)allenes to ketones and aldehydes. A regiocontrolled synthesis of homopropargylic alcohols
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This article has been cited by 30 ACS Journal articles (5 most recent appear below).
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Metal-Catalyzed Rearrangement of Cyclopropenes to Allenes
Jingwei Li , Chunrui Sun , Silviya Demerzhan , and Daesung LeeJournal of the American Chemical Society 0 (ja),Metal-Catalyzed Rearrangement of Cyclopropenes to Allenes
Jingwei Li , Chunrui Sun , Silviya Demerzhan , and Daesung LeeJournal of the American Chemical Society 0 (ja),A novel transition metal-catalyzed rearrangement of silylated cyclopropenes to the corresponding allenes is described. The presence of both the trimethylsily group on the cyclopropene and platinum catalyst are crucial for this rearrangement.
Diastereodivergent Behavior of Alkyl- versus Cyano- Allenylcuprates towards Aldehydes: a Key Role for Lithium
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Emmanuel Vrancken , Hélène Gerard , David Linder , Souad Ouizem , Nacira Alouane , Eve Roubineau , Kamel Bentayeb , Jerome Marrot , and Pierre MangeneyJournal of the American Chemical Society 0 (ja),The stereodivergent behavior of allenyl(cyano)- and allenyl(alkyl)- cuprates toward aldehydes, providing a selective preparation of both syn or anti homopropargylic alcohols, is described. This study, which combines both experimental and theoretical ...
Catalytic Asymmetric Propargylation
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Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenylsilanes and Their Application to SE2′ Chirality Transfer Reactions
Masamichi Ogasawara, Atsushi Okada, Velusamy Subbarayan, Sebastian Sörgel, and Tamotsu TakahashiOrganic Letters2010 12 (24), 5736-5739Palladium-Catalyzed Asymmetric Synthesis of Axially Chiral Allenylsilanes and Their Application to SE2′ Chirality Transfer Reactions
Masamichi Ogasawara, Atsushi Okada, Velusamy Subbarayan, Sebastian Sörgel, and Tamotsu TakahashiOrganic Letters2010 12 (24), 5736-5739Stepwise application of the Pd-catalyzed SN2′ reaction and the desilylative SE2′ reaction to the ambivalent 2-bromo-1-silyl-1,3-dienes provides a novel route to the highly enantioselective construction of tertiary and quaternary propargylic stereogenic ...
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- Published In Issue October, 1986
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