(Trimethylsilyl)allenes as propargylic anion equivalents: synthesis of homopropargylic alcohols and ethers

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This article has been cited by 22 ACS Journal articles (5 most recent appear below).

• 

  Chiral Brønsted Acid Catalyzed Enantioselective Propargylation of Aldehydes with Allenylboronate

  Leleti Rajender Reddy
  Organic Letters2012 Article ASAP

  • Chiral Brønsted Acid Catalyzed Enantioselective Propargylation of Aldehydes with Allenylboronate

    Leleti Rajender Reddy
    Organic Letters2012 Article ASAP

    A highly enantioselective chiral Brønsted acid catalyzed propargylation of aldehydes with allenylboronate is described. The reaction is shown to be practical and quite general with a broad substrate scope covering aryl, polyaryl, heteroaryl, α,β-...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Total Synthesis of (−)-Histrionicotoxin

  Yohei Adachi, Noriyuki Kamei, Satoshi Yokoshima, and Tohru Fukuyama
  Organic Letters2011 Article ASAP

  • Total Synthesis of (−)-Histrionicotoxin

    Yohei Adachi, Noriyuki Kamei, Satoshi Yokoshima, and Tohru Fukuyama
    Organic Letters2011 Article ASAP

    A total synthesis of (−)-histrionicotoxin was achieved. Our synthesis features preparation of a pseudosymmetrical dienyne through chirality transfer from an allenylsilane, a dienyne metathesis to produce the bicyclo [5.4.0] system in optically active form,...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Stereoselectivity in Nucleophilic Additions to 3-Azidoalkanals

  Chan Woo Huh, Chad Schroeder, Gurpreet Singh, and Jeffrey Aubé
  The Journal of Organic Chemistry2011 76 (9), 3160-3165

  • Stereoselectivity in Nucleophilic Additions to 3-Azidoalkanals

    Chan Woo Huh, Chad Schroeder, Gurpreet Singh, and Jeffrey Aubé
    The Journal of Organic Chemistry2011 76 (9), 3160-3165

    The stereoselectivity of nucleophilic additions to 3-azidoalkanals was investigated. Non-chelating, BF3·OEt2-mediated Sakurai addition to 3-azidoalkanals afforded 1,3-anti products, whereas use of a chelating Lewis acid, TiCl4, resulted in 1,3-syn ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Helical Chiral 2,2′-Bipyridine N- Monoxides as Catalysts in the Enantioselective Propargylation of Aldehydes with Allenyltrichlorosilane

  Jinshui Chen, Burjor Captain, and Norito Takenaka
  Organic Letters2011 13 (7), 1654-1657

  • Helical Chiral 2,2′-Bipyridine N- Monoxides as Catalysts in the Enantioselective Propargylation of Aldehydes with Allenyltrichlorosilane

    Jinshui Chen, Burjor Captain, and Norito Takenaka
    Organic Letters2011 13 (7), 1654-1657

    A highly enantioselective synthesis of homopropargylic alcohols is achieved by using the new helical chiral 2,2′-bipyridine N-monoxide catalyst and allenyltrichlorosilane. This method can be further extended to the enantio- and regioselective ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Catalytic Asymmetric Propargylation

  Chang-Hua Ding and Xue-Long Hou
  Chemical Reviews2011 111 (3), 1914-1937

  • Catalytic Asymmetric Propargylation

    Chang-Hua Ding and Xue-Long Hou
    Chemical Reviews2011 111 (3), 1914-1937
    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

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