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Highly Efficient Iridium-Catalyzed Oxidation of Organosilanes to Silanols

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Youngjun Lee,^† Dong Seomoon,^† Sundae Kim,^† Hoon Han,^‡ Sukbok Chang,^‡ and Phil Ho Lee*^†

Department of Chemistry, Kangwon National University, Chunchon 200-701, Republic of Korea, and Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea phlee@kangwon.ac.kr

J. Org. Chem., 2004, 69 (5), pp 1741–1743

DOI: 10.1021/jo035647r

Publication Date (Web): February 3, 2004

†

Kangwon National University.

‡

Korea Advanced Institute of Science and Technology.

Corresponding author. Phone: +82 33 250 8493. Fax: +82 33 253 7582.

Abstract

Hydrolytic oxidation of organosilanes to the corresponding silanols can be performed highly efficiently with a catalyst system of [IrCl(C₈H₁₂)]₂ under essentially neutral and mild conditions, and various types of silanols are produced in good to excellent yields.

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Published In Issue March 05, 2004
Received November 9, 2003

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Highly Efficient Iridium-Catalyzed Oxidation of Organosilanes to Silanols

Abstract

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History

Recommend & Share

Related Content

Highly Selective and Practical Hydrolytic Oxidation of Organosilanes to Silanols Catalyzed by a Ruthenium Complex

Mild and General Cross-Coupling of (α-Alkoxyvinyl)silanols and -silyl Hydrides

Hydrogen Production from Hydrolytic Oxidation of Organosilanes Using a Cationic Oxorhenium Catalyst

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