Stereospecific Addition of H−P Bond to Alkenes:  A Simple Method for the Preparation of (R_P)-Phenylphosphinates

Related Content

• Retention of Configuration on the Oxidative Addition of P−H Bond to Platinum (0) Complexes:  The First Straightforward Synthesis of Enantiomerically Pure P-Chiral Alkenylphosphinates via Palladium-Catalyzed Stereospecific Hydrophosphinylation of AlkynesJournal of the American Chemical Society

  • Retention of Configuration on the Oxidative Addition of P−H Bond to Platinum (0) Complexes:  The First Straightforward Synthesis of Enantiomerically Pure P-Chiral Alkenylphosphinates via Palladium-Catalyzed Stereospecific Hydrophosphinylation of Alkynes

    Li-Biao Han, Chang-Qiu Zhao, Shun-ya Onozawa, Midori Goto, and Masato Tanaka
    Journal of the American Chemical Society 2002 124 (15), pp 3842–3843

    Abstract: The oxidative addition of pure (R_P)-menthyl phenylphosphinate 1 to a platinum (0) complex proceeds readily with retention of configuration at the chiral phosphorus center which was unambiguously confirmed by an X-ray analysis. In the presence of a ...

    Abstract | Full Text HTML | Hi-Res PDF
• Palladium-Catalyzed Insertion of Isocyanides into P(O)−H Bonds:  Selective Formation of Phosphinoyl Imines and BisphosphinoylaminomethanesJournal of the American Chemical Society

  • Palladium-Catalyzed Insertion of Isocyanides into P(O)−H Bonds:  Selective Formation of Phosphinoyl Imines and Bisphosphinoylaminomethanes

    Takayoshi Hirai and Li-Biao Han
    Journal of the American Chemical Society 2006 128 (23), pp 7422–7423

    Abstract: Palladium and rhodium catalyzed the addition of H-phosphine oxides to isocyanides to selectively generate α-iminophosphine oxides and bisphosphinoylaminomethanes, respectively.

    Abstract | Full Text HTML | Hi-Res PDF
• Efficient and Selective Nickel-Catalyzed Addition of H−P(O) and H−S Bonds to AlkynesJournal of the American Chemical Society

  • Efficient and Selective Nickel-Catalyzed Addition of H−P(O) and H−S Bonds to Alkynes

    Li-Biao Han, Chen Zhang, Hideaki Yazawa, and Shigeru Shimada
    Journal of the American Chemical Society 2004 126 (16), pp 5080–5081

    Abstract: The cheap nickel catalysts are more reactive than the corresponding noble metal catalysts in the catalytic additions of a variety of P(O)−H bonds and an S−H bond to alkynes, affording regio- and stereoselectively both the Markovnikov and the anti-...

    Abstract | Full Text HTML | Hi-Res PDF

Other ACS content by these authors:

• Li-Biao Han
• Chang-Qiu Zhao