RuCl3-Catalyzed Oxidation of Iodoarenes with Peracetic Acid:  New Facile Preparation of Iodylarenes

Alexey Y. Koposov,† Rashad R. Karimov,† Andrey A. Pronin,† Tatyana Skrupskaya,† Mekhman S. Yusubov,‡ and Viktor V. Zhdankin*†
Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota, 55812, and The Siberian State Medical University, Tomsk, Russia vzhdanki@d.umn.edu
J. Org. Chem., 2006, 71 (26), pp 9912–9914
DOI: 10.1021/jo062073s
Publication Date (Web): November 29, 2006
Copyright © 2006 American Chemical Society
†

 University of Minnesota Duluth.

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‡

 The Siberian State Medical University.

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*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

Abstract

Abstract Image

New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF3 groups in the aromatic ring.

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History

  • Published In Issue December 22, 2006
  • Received October 6, 2006

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