An Efficient One-Pot Synthesis of Unsymmetrical Ethers:  A Directly Reductive Deoxygenation of Esters Using an InBr₃/Et₃SiH Catalytic System

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Abstract

This study describes a novel one-pot procedure for a directly reductive conversion of the carbonyl function of esters to the corresponding ethers by Et₃SiH in the presence of a catalytic amount of InBr₃.

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This article has been cited by 3 ACS Journal articles (3 most recent appear below).

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    Yoshihiro Inamoto, Yoshihiro Nishimoto, Makoto Yasuda, and Akio Baba
    Organic Letters2012 Article ASAP

    An indium triiodide catalyst promoted the direct transformation from esters to β-hydroxycarbonyl compounds using hydrosilanes and silyl enolates by a one-stage process. Various esters were applicable, and the high chemoselectivity of this system brings ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
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  Nucleophilic Iron Catalysis in Transesterifications: Scope and Limitations

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  The Journal of Organic Chemistry2010 75 (11), 3715-3721

  • Nucleophilic Iron Catalysis in Transesterifications: Scope and Limitations

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    The Journal of Organic Chemistry2010 75 (11), 3715-3721

    The ester bond is one of the most common structural motifs found in nature. Apart from the condensation between an acid and an alcohol, transesterifications represent another mechanistic alternative for the preparation of this compound class. The present ...

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• 

  FeCl₃·6H₂O Catalyzed Disproportionation of Allylic Alcohols and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol

  Jialiang Wang, Wen Huang, Zhengxing Zhang, Xu Xiang, Ruiting Liu and Xigeng Zhou
  The Journal of Organic Chemistry2009 74 (9), 3299-3304

  • FeCl₃·6H₂O Catalyzed Disproportionation of Allylic Alcohols and Selective Allylic Reduction of Allylic Alcohols and Their Derivatives with Benzyl Alcohol

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    The Journal of Organic Chemistry2009 74 (9), 3299-3304

    Iron chloride has been found to be an efficient catalyst for the disproportionation of allylic alcohols, which provides a convenient method for selective transformation of allylic alcohols to alkenes and α,β-unsaturated ketones. Furthermore, this ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

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