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Terminal Olefins from Aldehydes through Enol Triflate Reduction

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Sushil K. Pandey, Andrew E. Greene, and Jean-François Poisson*

Département de Chimie Moléculaire (SERCO), CNRS, UMR-5250, ICMG FR-2607, Université Joseph Fourier, BP-53, 38041 Grenoble Cedex 9, France jean-francois.poisson@ujf-grenoble.fr

J. Org. Chem., 2007, 72 (20), pp 7769–7770

DOI: 10.1021/jo071151o

Publication Date (Web): September 8, 2007

Abstract

The transformation of aldehydes into terminal olefins through reduction of the corresponding enol triflates is described. The method is effective with both linear and α-branched aldehydes.

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Published In Issue September 28, 2007
Received June 4, 2007

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Terminal Olefins from Aldehydes through Enol Triflate Reduction

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Olefin synthesis via organometallic coupling reactions of enol triflatesOlefin synthesis via organometallic coupling reactions of enol triflates

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A Stereocontrolled Synthesis of (+)-Saxitoxin

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