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Oppenauer Oxidation of Secondary Alcohols with 1,1,1-Trifluoroacetone as Hydride Acceptor
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Abstract

1,1,1-Trifluoroacetone (2a) reacts as a hydride-acceptor in the Oppenauer oxidation of secondary alcohols (1) in the presence of diethylethoxyaluminum. The oxidant allows for selective oxidation of secondary alcohols in the presence of primary alcohols.
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This article has been cited by 1 ACS Journal articles (1 most recent appear below).

How Trifluoroacetone Interacts with Water
Laura B. Favero, Luca Evangelisti, Assimo Maris, Alicia Vega-Toribio, Alberto Lesarri, and Walther CaminatiThe Journal of Physical Chemistry A2011 115 (34), 9493-9497How Trifluoroacetone Interacts with Water
Laura B. Favero, Luca Evangelisti, Assimo Maris, Alicia Vega-Toribio, Alberto Lesarri, and Walther CaminatiThe Journal of Physical Chemistry A2011 115 (34), 9493-9497The rotational spectra of five isotopologues of the molecular adduct 1,1,1-trifluoroacetone−water have been assigned using pulsed-jet Fourier-transform microwave spectroscopy. All rotational transitions appear as doublets, due to the internal rotation of ...
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History
- Published In Issue November 23, 2007
- Received July 26, 2007
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