Cart
Note
An Efficient 1,2-Chelation-Controlled Reduction of Protected Hydroxy Ketones via Red-Al
Full Text HTML
Hi-Res PDF
Your current credentials do not allow retrieval of the full text.
Purchase the full-text
- PDF/HTML,
figures/images,
references and tables,
(where available)
Department of Chemistry, 250 Hackberry Lane, The University of Alabama, Tuscaloosa, Alabama 35487-0336
J. Org. Chem., 2008, 73 (9), pp 3638–3641
DOI: 10.1021/jo800150x
Publication Date (Web): March 22, 2008
Copyright © 2008 American Chemical Society
Abstract
In this paper, we have demonstrated that Red-Al is an efficient chelation-controlled reducing reagent for acyclic acetal (i.e., MOM, MEM, SEM, and BOM) protected α-hydroxy ketones. Typically, diastereomeric ratios (dr) ranged from 5 to 20:1 for the 1,2-anti-diols in good to excellent yields.
Citing Articles
Citation data is made available by participants in CrossRef's Cited-by Linking service. For a more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder.
Tools
-
Add to Favorites
-
Download Citation
-
Email a Colleague -
Permalink
Order Reprints
Rights & Permissions
Citation Alerts
History
- Published In Issue May 02, 2008
- Article ASAPMarch 22, 2008
- Received: January 21, 2008
ACS
Network
Facebook
Tweet This
CiteULike
Newsvine
Digg This
Delicious
