First Kinetic Discrimination Between Carbon and Oxygen Reactivity of Enols

Related Content

• Traceless Chiral Auxiliaries for the Allene Ether Nazarov CyclizationThe Journal of Organic Chemistry

  • Traceless Chiral Auxiliaries for the Allene Ether Nazarov Cyclization

    April R. Banaag and Marcus A. Tius
    The Journal of Organic Chemistry 2008 73 (21), pp 8133–8141
    Abstract | Full Text HTML | PDF w/ Links | Hi-Res PDF
• Vilsmeier−Haack Reaction of 1-Cyclopropyl-2-arylethanonesThe Journal of Organic Chemistry

  • Vilsmeier−Haack Reaction of 1-Cyclopropyl-2-arylethanones

    Xiang-Ying Tang and Min Shi
    The Journal of Organic Chemistry 2008 73 (21), pp 8317–8320

    Abstract: A convenient and efficient method to synthesize 3-(2-chloroethyl)-5-aryl-4H-pyran-4-ones 2 and 2-chloro-3-(2-chloroethyl)-1-naphthaldehydes 3 in moderate to good yields was developed via the Vilsmeier−Haack reaction of readily available 1-cyclopropyl-2-...

    Abstract | Full Text HTML | PDF w/ Links | Hi-Res PDF
• Substituent Effects on the Rearrangements of Cyclohexyl to Cyclopentyl Radicals Involving Avermectin-Related RadicalsThe Journal of Organic Chemistry

  • Substituent Effects on the Rearrangements of Cyclohexyl to Cyclopentyl Radicals Involving Avermectin-Related Radicals

    Jennifer A. R. Luft, Tammo Winkler, Fiona M. Kessabi and K. N. Houk
    The Journal of Organic Chemistry 2008 73 (21), pp 8175–8181

    Abstract: The rearrangement of a substituted cyclohexyl radical to a cyclopentylmethyl radical on the skeleton of avermectin B₁ has been investigated using density functional (UB3LYP/6-31G(d)) and G3MP2B3 computational methods. The rearrangement is preferred when ...

    Abstract | Full Text HTML | PDF w/ Links | Hi-Res PDF

Other ACS articles by these authors:

• Luis Garca-Ro
• Juan C. Mejuto
• Mercedes Paraj
• Moiss Prez-Lorenzo