Article
Stereoselective Synthesis of meso-1,5-Cyclodecadiynes
Abstract

Reduction of Co2(CO)6-stabilized bis-propargyl cations with cobaltocene occurs with high meso-diastereoselectivity (up to 97%), affording, upon decomplexation, meso-1,5-cyclodecadiynes, otherwise hardly accessible.
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History
- Published In Issue November 20, 2009
- Article ASAPOctober 15, 2009
- Received: July 01, 2009
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