Remarkable Effect of Ethylene Gas in the Intramolecular Enyne Metathesis of Terminal Alkynes

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This article has been cited by 72 ACS Journal articles (5 most recent appear below).

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  Ethylene-Promoted versus Ethylene-Free Enyne Metathesis

  Anne G. D. Grotevendt, Justin A. M. Lummiss, Melanie L. Mastronardi, and Deryn E. Fogg
  Journal of the American Chemical Society2011 133 (40), 15918-15921

  • Ethylene-Promoted versus Ethylene-Free Enyne Metathesis

    Anne G. D. Grotevendt, Justin A. M. Lummiss, Melanie L. Mastronardi, and Deryn E. Fogg
    Journal of the American Chemical Society2011 133 (40), 15918-15921

    The role of ethylene in promoting metathesis of acetylenic enynes is probed within the context of ring-closing enyne metathesis, using first- and second-generation Grubbs catalysts. Under inert atmosphere, rapid catalyst deactivation is observed by ...

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• 

  From Highly Enantioselective Catalytic Reaction of 1,3-Diynes with Aldehydes to Facile Asymmetric Synthesis of Polycyclic Compounds

  Mark Turlington, Yuhao Du, Samuel G. Ostrum, Vishaka Santosh, Kathryne Wren, Tony Lin, Michal Sabat, and Lin Pu
  Journal of the American Chemical Society2011 133 (30), 11780-11794

  • From Highly Enantioselective Catalytic Reaction of 1,3-Diynes with Aldehydes to Facile Asymmetric Synthesis of Polycyclic Compounds

    Mark Turlington, Yuhao Du, Samuel G. Ostrum, Vishaka Santosh, Kathryne Wren, Tony Lin, Michal Sabat, and Lin Pu
    Journal of the American Chemical Society2011 133 (30), 11780-11794

    (S)-1,1′-Binaphth-2-ol (BINOL) in combination with ZnEt2, Ti(OiPr)4, and biscyclohexylamine was found to catalyze the highly enantioselective (83–95% ee) addition of various 1,3-diynes to aldehydes of diverse structures. This method provides a convenient ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Platinum(II) Chloride-Catalyzed Stereoselective Domino Enyne Isomerization/Diels−Alder Reaction

  Mathias Schelwies, Andreas Farwick, Frank Rominger, and Günter Helmchen
  The Journal of Organic Chemistry2010 75 (22), 7917-7919

  • Platinum(II) Chloride-Catalyzed Stereoselective Domino Enyne Isomerization/Diels−Alder Reaction

    Mathias Schelwies, Andreas Farwick, Frank Rominger, and Günter Helmchen
    The Journal of Organic Chemistry2010 75 (22), 7917-7919

    Chiral 1,6-enynes were prepared via Ir-catalyzed allylic substitutions. Their platinum(II) chloride-catalyzed domino enyne isomerization/Diels−Alder reaction provided stereoselective access to complex heterocycles. Very high diastereoselectivity was ...

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  Asymmetric Allylic Alkylation in Combination with Ring-Closing Metathesis for the Preparation of Chiral N-Heterocycles

  Johannes F. Teichert, Suyan Zhang, Anthoni W. van Zijl, Jan Willem Slaa, Adriaan J. Minnaard, and Ben L. Feringa
  Organic Letters2010 12 (20), 4658-4660

  • Asymmetric Allylic Alkylation in Combination with Ring-Closing Metathesis for the Preparation of Chiral N-Heterocycles

    Johannes F. Teichert, Suyan Zhang, Anthoni W. van Zijl, Jan Willem Slaa, Adriaan J. Minnaard, and Ben L. Feringa
    Organic Letters2010 12 (20), 4658-4660

    Asymmetric copper-catalyzed allylic substitution with methylmagnesium bromide is employed in combination with ring-closing olefin metathesis or ene−yne metathesis to achieve the synthesis of chiral, unsaturated nitrogen heterocycles. The resulting six- ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
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  Diastereoselective Synthesis of P-Stereogenic Heterocycles via Enyne Ring-Closing Metathesis

  James Stephen Harvey, Guy T. Giuffredi and Véronique Gouverneur
  Organic Letters2010 12 (6), 1236-1239

  • Diastereoselective Synthesis of P-Stereogenic Heterocycles via Enyne Ring-Closing Metathesis

    James Stephen Harvey, Guy T. Giuffredi and Véronique Gouverneur
    Organic Letters2010 12 (6), 1236-1239

    A range of P-containing ene-diynes suitable for desymmetrization was prepared via a two-step process starting from phosphorus oxychloride. In the presence of the Hoveyda−Grubbs II catalyst, these substrates underwent diastereoselective enyne ring-...

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