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Fast and Exothermic Reaction of CO₂ and Li₃N into C–N-Containing Solid Materials

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Yun Hang Hu* and Yan Huo

Department of Materials Science and Engineering, Michigan Technological University, 1400 Townsend Drive, Houghton, Michigan 49931-1295, United States

J. Phys. Chem. A, 2011, 115 (42), pp 11678–11681

DOI: 10.1021/jp205499e

Publication Date (Web): September 12, 2011

Tel.: 906-4872261. E-mail: yunhangh@mtu.edu.

Section:

Electrochemical, Radiational, and Thermal Energy Technology

Abstract

The conversion of CO₂ to valuable compounds, which is considered as an effective approach to solve the global warming, represents a great challenge due to the high stability and low reactivity of CO₂. Herein, thermodynamic calculations predicted the feasibility of exothermic reactions between CO₂ and Li₃N into two important solid materials—carbon nitride and lithium cyanamide. Furthermore, the feasibility was confirmed by experiments, namely, the fast reaction between CO₂ and Li₃N produced crystal lithium cyanamide and amorphous carbon nitrides. This provides a novel process to control CO₂ emissions.

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History

Published In Issue October 27, 2011
Article ASAPSeptember 30, 2011
Just Accepted ManuscriptSeptember 12, 2011
Received: June 12, 2011
Revised: September 09, 2011

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Fast and Exothermic Reaction of CO₂ and Li₃N into C–N-Containing Solid Materials