Formation of Monolayer Graphene by Annealing Sacrificial Nickel Thin Films

A. J. Pollard, R. R. Nair, S. N. Sabki, C. R. Staddon, L. M. A. Perdigao, C. H. Hsu, J. M. Garfitt, S. Gangopadhyay, H. F. Gleeson, A. K. Geim and P. H. Beton*
School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD, U.K., and School of Physics and Astronomy, University of Manchester, Schuster Laboratory, Brunswick Street, Manchester M13 9PL, U.K.
J. Phys. Chem. C, 2009, 113 (38), pp 16565–16567
DOI: 10.1021/jp906066z
Publication Date (Web): September 1, 2009
Copyright © 2009 American Chemical Society
* To whom correspondence should be addressed. E-mail: peter.beton@nottingham.ac.uk. Tel: Tel: +44 115 9515129. Fax: +44 115 9515180., †

University of Nottingham.

, ‡

University of Manchester.

Abstract

Abstract Image

Graphene films have been formed by annealing Ni thin films at 800 °C under vacuum conditions. The Ni thin films are deposited on Si/SiO2 and, following annealing, have a polycrystalline morphology with grain sizes on the order of 1 μm. Following growth, the Ni is removed by etching, and the graphene is transferred as a single continuous layer onto a separate surface. The fraction of monolayer graphene is investigated using optical and electron microscopy and Raman spectroscopy and is shown to be >75%.

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History

  • Published In Issue September 24, 2009
  • Article ASAPSeptember 01, 2009
  • Received: June 29, 2009
    Revised: August 4, 2009

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