Experimental and Theoretical Studies of Transport through Large Scale, Partially Aligned Arrays of Single-Walled Carbon Nanotubes in Thin Film Type Transistors

C. Kocabas, N. Pimparkar,§ O. Yesilyurt, S. J. Kang, M. A. Alam,*§ and J. A. Rogers*#+
Departments of Physics, Materials and Science Engineering, Chemistry, and Electrical and Computer Engineering, Beckman Institute, and Frederick Seitz Materials Research Laboratory, University of Illinois, Urbana-Champaign 61801, School of Electrical and Computer Engineering, Purdue University, West Lafayette, Indiana 47907-1285, and Department of Materials Science and Nanotechnology, Bilkent University, 06800 Bilkent, Ankara, Turkey
Nano Lett., 2007, 7 (5), pp 1195–1202
DOI: 10.1021/nl062907m
Publication Date (Web): March 30, 2007
Copyright © 2007 American Chemical Society

Abstract

Abstract Image

Gate-modulated transport through partially aligned films of single-walled carbon nanotubes (SWNTs) in thin film type transistor structures are studied experimentally and theoretically. Measurements are reported on SWNTs grown by chemical vapor deposition with systematically varying degrees of alignment and coverage in transistors with a range of channel lengths and orientations perpendicular and parallel to the direction of alignment. A first principles stick-percolation-based transport model provides a simple, yet quantitative framework to interpret the sometimes counterintuitive transport parameters measured in these devices. The results highlight, for example, the dramatic influence of small degrees of SWNT misalignment on transistor performance and imply that coverage and alignment are correlated phenomena and therefore should be simultaneously optimized. The transport characteristics reflect heterogeneity in the underlying anisotropic metal−semiconductor stick-percolating network and cannot be reproduced by classical transport models.

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History

  • Published In Issue May 09, 2007
  • Received December 11, 2006
    Revised Manuscript Received March 7, 2007

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