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Nanodroplet Activated and Guided Folding of Graphene Nanostructures

Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, USA
Nano Lett., 2009, 9 (11), pp 3766–3771
DOI: 10.1021/nl9019616
Publication Date (Web): October 23, 2009
Copyright © 2009 American Chemical Society
* Corresponding author, pkral@uic.edu.

Abstract

Abstract Image

We demonstrate by molecular dynamics simulations that water nanodroplets can activate and guide the folding of planar graphene nanostructures. Once the nanodroplets are deposited at selected spots on the planar nanostructure, they can act as catalytic elements that initiate conformational changes and help to overcome deformation barriers associated with them. Nanodroplets can induce rapid bending, folding, sliding, rolling, and zipping of the planar nanostructures, which can lead to the assembly of nanoscale sandwiches, capsules, knots, and rings.

Movies showing nanodroplet-assisted folding. This material is available free of charge via the Internet at http://pubs.acs.org.

Citing Articles

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This article has been cited by 26 ACS Journal articles (5 most recent appear below).

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History

  • Published In Issue November 11, 2009
  • Article ASAPOctober 23, 2009
  • Received: June 18, 2009
    Revised: August 31, 2009

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