Nanodome Solar Cells with Efficient Light Management and Self-Cleaning

Jia Zhu, Ching-Mei Hsu, Zongfu Yu§, Shanhui Fan and Yi Cui*
Department of Electrical Engineering
Department of Materials Science and Engineering
§ Department of Applied Physics, Stanford University, Stanford, California 94305
Nano Lett., 2010, 10 (6), pp 1979–1984
DOI: 10.1021/nl9034237
Publication Date (Web): November 5, 2009
Copyright © 2009 American Chemical Society
* To whom correspondence should be addressed, yicui@stanford.edu.

Abstract

Abstract Image

Here for the first time, we demonstrate novel nanodome solar cells, which have periodic nanoscale modulation for all layers from the bottom substrate, through the active absorber to the top transparent contact. These devices combine many nanophotonic effects to both efficiently reduce reflection and enhance absorption over a broad spectral range. Nanodome solar cells with only a 280 nm thick hydrogenated amorphous silicon (a-Si:H) layer can absorb 94% of the light with wavelengths of 400−800 nm, significantly higher than the 65% absorption of flat film devices. Because of the nearly complete absorption, a very large short-circuit current of 17.5 mA/cm2 is achieved in our nanodome devices. Excitingly, the light management effects remain efficient over a wide range of incident angles, favorable for real environments with significant diffuse sunlight. We demonstrate nanodome devices with a power efficiency of 5.9%, which is 25% higher than the flat film control. The nanodome structure is not in principle limited to any specific material system and its fabrication is compatible with most solar manufacturing; hence it opens up exciting opportunities for a variety of photovoltaic devices to further improve performance, reduce materials usage, and relieve elemental abundance limitations. Lastly, our nanodome devices when modified with hydrophobic molecules present a nearly superhydrophobic surface and thus enable self-cleaning solar cells.

Keywords:

Nanocone; nanodome; solar cell; light trapping; photovoltaics

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History

  • Published In Issue June 09, 2010
  • Article ASAPNovember 05, 2009
  • Received: October 13, 2009
    Revised: November 01, 2009

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