Self-Assembly of Metal Oxides into Three-Dimensional Nanostructures: Synthesis and Application in Catalysis

Vivek Polshettiwar*, Babita Baruwati and Rajender S. Varma*
Sustainable Technology Division, National Risk Management Research Laboratory, U.S. Environmental Protection Agency, 26 West M.L.K. Drive, MS 443, Cincinnati, Ohio 45268
ACS Nano, 2009, 3 (3), pp 728–736
Publication Date (Web): February 11, 2009
Copyright © 2009 American Chemical Society
* Address correspondence to polshettiwar.vivek@epa.gov, varma.rajender@epa.gov.

Abstract

Abstract Image

Nanostructured metal (Fe, Co, Mn, Cr, Mo) oxides were fabricated under microwave irradiation conditions in pure water without using any reducing or capping reagent. The metal oxides self-assembled into octahedra, spheres, triangular rods, pine, and hexagonal snowflake-like three-dimensional morphologies. Pine-structured nano-iron oxides were studied as a novel support for various catalytic organic transformations.

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History

  • Published In Issue March 24, 2009
  • Article ASAPFebruary 11, 2009
  • Received: December 29, 2008
    Accepted: January 21, 2009

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