Convergence of Mechanistic Pathways in the Palladium(0)-Catalyzed Cross-Coupling of Alkenylsilacyclobutanes and Alkenylsilanols

Scott E. Denmark,* Daniel Wehrli, and Jun Young Choi
245 Roger Adams Laboratory, Department of Chemistry, University of Illinois, 600 South Mathews Avenue, Urbana, Illinois 61801
Org. Lett., 2000, 2 (16), pp 2491–2494
DOI: 10.1021/ol006170y
Publication Date (Web): July 13, 2000
Copyright © 2000 American Chemical Society
*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, denmark@scs.uiuc.edu

Abstract

Abstract Image

Alkenylsilacyclobutanes and alkenylsilanols react in palladium-catalyzed cross-coupling reactions via the same intermediate, produced in situ upon treatment of either starting material with tetrabutylammonium fluoride.

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History

  • Published In Issue August 10, 2000
  • Received June 7, 2000

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