Preparation of Silyl Enol Ethers Using (Bistrimethylsilyl)acetamide in Ionic Liquids

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Abstract

Ionic liquids have been used for the preparation of silyl enol ethers from aldehydes and ketones with (bistrimethylsilyl)acetamide (BSA) in good yields.

Citing Articles

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This article has been cited by 8 ACS Journal articles (5 most recent appear below).

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  Addition of TMS-Substituted Oxiranyl Anions to Acylsilanes. A Highly Stereoselective Approach to Tetrasubstituted (Z)-β-Hydroxy-α-TMS Silyl Enol Ethers

  Zhenlei Song, Leizhou Kui, Xianwei Sun, and Linjie Li
  Organic Letters2011 13 (6), 1440-1443

  • Addition of TMS-Substituted Oxiranyl Anions to Acylsilanes. A Highly Stereoselective Approach to Tetrasubstituted (Z)-β-Hydroxy-α-TMS Silyl Enol Ethers

    Zhenlei Song, Leizhou Kui, Xianwei Sun, and Linjie Li
    Organic Letters2011 13 (6), 1440-1443

    A highly stereoselective approach to novel tetrasubstituted (Z)-β-hydroxy-α-TMS silyl enol ethers is described. The reaction proceeds via a sequential addition/[1,2]-Brook rearrangement/epoxide-opening process of TMS-substituted oxiranyl anions with ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Binding Characteristics and Molecular Mechanism of Interaction between Ionic Liquid and DNA

  Yuanhua Ding, Lin Zhang, Ju Xie and Rong Guo
  The Journal of Physical Chemistry B2010 114 (5), 2033-2043

  • Binding Characteristics and Molecular Mechanism of Interaction between Ionic Liquid and DNA

    Yuanhua Ding, Lin Zhang, Ju Xie and Rong Guo
    The Journal of Physical Chemistry B2010 114 (5), 2033-2043

    The binding characteristics and molecular mechanism of the interaction between a typical ionic liquid (IL), 1-butyl-3-methylimidazolium chloride ([bmim]Cl), as a green solvent and DNA were investigated for the first time by conductivity measurements, ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Effect of Ionic Liquids on the Aggregation Behavior of PEO-PPO-PEO Block Copolymers in Aqueous Solution

  Lily Zheng, Chen Guo, Jing Wang, Xiangfeng Liang, Shu Chen, Junhe Ma, Bin Yang, Yangyang Jiang, and Huizhou Liu
  The Journal of Physical Chemistry B2007 111 (6), 1327-1333

  • Effect of Ionic Liquids on the Aggregation Behavior of PEO-PPO-PEO Block Copolymers in Aqueous Solution

    Lily Zheng, Chen Guo, Jing Wang, Xiangfeng Liang, Shu Chen, Junhe Ma, Bin Yang, Yangyang Jiang, and Huizhou Liu
    The Journal of Physical Chemistry B2007 111 (6), 1327-1333

    Effect of 1-butyl-3-methyl-imidazolium bromide (BmimBr) on the aggregation behavior of PEO-PPO-PEO Pluronic P104 aqueous solution was studied by Fourier transform infrared (FTIR) spectroscopy, freeze fracture transmission electron microscopy (FF-TEM), ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Comparison of Dansylated Aminopropyl Controlled Pore Glass Solvated by Molecular and Ionic Liquids

  Phillip M. Page, Taylor A. McCarty, Gary A. Baker, Sheila N. Baker, and Frank V. Bright
  Langmuir2007 23 (2), 843-849

  • Comparison of Dansylated Aminopropyl Controlled Pore Glass Solvated by Molecular and Ionic Liquids

    Phillip M. Page, Taylor A. McCarty, Gary A. Baker, Sheila N. Baker, and Frank V. Bright
    Langmuir2007 23 (2), 843-849

    We compare how (i) four ionic liquids (ILs) (1-butyl-3-methylimidazolium tetrafluoroborate ([C4mim][BF4]), 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C4mim][Tf2N]), 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Behavior of Pyrene End-Labeled Poly(dimethylsiloxane) Polymer Tails in Mixtures of 1-Butyl-3-methylimidazolium Bis(trifluoromethyl)sulfonylimide and Toluene

  Wendy E. Gardinier, Gary A. Baker, Sheila N. Baker, and Frank V. Bright
  Macromolecules2005 38 (20), 8574-8582

  • Behavior of Pyrene End-Labeled Poly(dimethylsiloxane) Polymer Tails in Mixtures of 1-Butyl-3-methylimidazolium Bis(trifluoromethyl)sulfonylimide and Toluene

    Wendy E. Gardinier, Gary A. Baker, Sheila N. Baker, and Frank V. Bright
    Macromolecules2005 38 (20), 8574-8582

    We report on the steady-state and time-resolved fluorescence of a linear poly(dimethylsiloxane) polymer that is end-labeled with pyrene (Py-PDMS-Py, Mn = 3100, Mw/Mn = 1.07) when it is dissolved at low concentration in an ionic liquid,1-butyl-3-...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

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