Synthesis of (+)-Galiellalactone. Absolute Configuration of Galiellalactone

Martin Johansson and Olov Sterner*
Department of Organic and Bioorganic Chemistry, Lund University, POB 124, S-221 00 Lund, Sweden
Org. Lett., 2001, 3 (18), pp 2843–2845
DOI: 10.1021/ol016286+
Publication Date (Web): August 4, 2001
Copyright © 2001 American Chemical Society
*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, olov.sterner@orgk2.lth.se

Abstract

Abstract Image

(+)-Galiellalactone was synthesized starting from (R)-(+)-pulegone. Natural and synthetic galiellalactone have opposite optical rotations, demonstrating that the structure of the natural product is 1a.

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History

  • Published In Issue September 06, 2001
  • Received June 15, 2001

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