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Letter

B(C₆F₅)₃-Catalyzed Allylation of Secondary Benzyl Acetates with Allylsilanes

Supporting Info

Michael Rubin and Vladimir Gevorgyan*

Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, Illinois 60607-7061

Org. Lett., 2001, 3 (17), pp 2705–2707

DOI: 10.1021/ol016300i

Publication Date (Web): July 21, 2001

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, vlad@uic.edu

Abstract

A highly effective protocol for allylation of secondary benzylic alcohol derivatives with allylsilanes in the presence of catalytic amounts of B(C₆F₅)₃ has been developed. Some additional functionalities, such as bromo, acetoxy, and primary benzyloxy groups, were tolerated under these conditions.

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History

Published In Issue August 23, 2001
Received June 19, 2001

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Letter

B(C₆F₅)₃-Catalyzed Allylation of Secondary Benzyl Acetates with Allylsilanes