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Letter

An Exceptional Hydroboration of Substituted Fluoroolefins Providing Tertiary Alcohols

Supporting Info

P. Veeraraghavan Ramachandran* and Michael P. Jennings

Herbert C. Brown Center for Borane Research, Department of Chemistry, Purdue University, West Lafayette, Indiana 47907-1393

Org. Lett., 2001, 3 (23), pp 3789–3790

DOI: 10.1021/ol016779e

Publication Date (Web): October 20, 2001

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, chandran@purdue.edu

Abstract

A rare hydroboration−oxidation providing 3°-alcohols has been achieved in the case of 1,1,2-perfluoroalkyl(aryl)ethylenes. The hydroboration of substituted perfluoroalkyl(aryl)ethylenes with dichloroborane reveals that the regioselectivity does not entirely depend on the electronics of the fluoroolefins.

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Published In Issue November 15, 2001
Received September 19, 2001

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Letter

An Exceptional Hydroboration of Substituted Fluoroolefins Providing Tertiary Alcohols

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Hydroboration with Pyridine Borane at Room Temperature

Chemoselectivity: The Mother of Invention in Total Synthesis

Critical Role of Catalysts and Boranes for Controlling the Regioselectivity in the Rhodium-Catalyzed Hydroboration of Fluoroolefins

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