Platinum Oxide (PtO2): A Potent Hydrosilylation Catalyst

Nicolas Sabourault,† Gérard Mignani,‡ Alain Wagner,*† and Charles Mioskowski*†
Laboratoire de Synthse Bio-Organique, UMR 7514, Facult de Pharmacie, Universit Louis Pasteur, 74 route du Rhin, B.P. 24, 67401 Illkirch Cedex, France, and Rhodia Silicones Lyon, 55 av. des Frres Perret, B.P. 22, 69191 Saint-Fons Cedex, France
Org. Lett., 2002, 4 (13), pp 2117–2119
DOI: 10.1021/ol025658r
Publication Date (Web): June 4, 2002
Copyright © 2002 American Chemical Society
†

 Laboratorie de Synthèse Bio-Organique.

,
‡

 Rhodia Silicones Lyon.

,
*

 Email for corresponding author A.W.:  alwag@aspirine.u-strsbg.fr.

, mioskow@aspirine.u-strasbg.fr

Abstract

Abstract Image

Platinum oxide was found to be a versatile and powerful hydrosilylation catalyst upon a wide variety of functionalized alkenes and especially aminated alkenes. Moreover, highly reproducible results and easy removal make this new catalyst a useful tool for hydrosilylation reaction.

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History

  • Published In Issue June 27, 2002
  • Received February 3, 2002
    Revised April 21, 2002

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