Prev. Article Next Article Table of Contents

Letter

Rhodium(I)-Catalyzed Silylation of Aryl Halides with Triethoxysilane: Practical Synthetic Route to Aryltriethoxysilanes

Supporting Info

Miki Murata,* Masanori Ishikura, Masayuki Nagata, Shinji Watanabe, and Yuzuru Masuda*

Department of Materials Science, Kitami Institute of Technology, Kitami 090-8507, Japan

Org. Lett., 2002, 4 (11), pp 1843–1845

DOI: 10.1021/ol025770p

Publication Date (Web): May 3, 2002

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, muratamk@mail.kitami-it.ac.jp

Abstract

The specific silylation of aryl iodides and bromides with triethoxysilane (EtO)₃SiH in the presence of NEt₃ and a catalytic amount of [Rh(cod)(MeCN)₂]BF₄ provides the corresponding aryltriethoxysilanes in high yield.

View: Full Text HTML | Hi-Res PDF

Tools

SciFinder Links

History

Published In Issue May 30, 2002
Received February 22, 2002

Recommend & Share

Related Content

Synthesis of Arylsilanes via Palladium(0)-Catalyzed Silylation of Aryl Halides with HydrosilaneThe Journal of Organic Chemistry
- Synthesis of Arylsilanes via Palladium(0)-Catalyzed Silylation of Aryl Halides with Hydrosilane
  Miki Murata, Katsuhiro Suzuki, Shinji Watanabe, and Yuzuru Masuda
  The Journal of Organic Chemistry 1997 62 (24), pp 8569–8571
  Abstract | Full Text HTML | Hi-Res PDF
Improved Synthesis of Aryltriethoxysilanes via Palladium(0)-Catalyzed Silylation of Aryl Iodides and Bromides with TriethoxysilaneThe Journal of Organic Chemistry
- Improved Synthesis of Aryltriethoxysilanes via Palladium(0)-Catalyzed Silylation of Aryl Iodides and Bromides with Triethoxysilane
  Amy S. Manoso and Philip DeShong
  The Journal of Organic Chemistry 2001 66 (22), pp 7449–7455
  Abstract: The scope of the palladium-catalyzed silylation of aryl halides with triethoxysilane has been expanded to include aryl bromides. A more general Pd(0) catalyst/ligand system has been developed that activates bromides and iodides: palladium(0) ...
  Abstract | Full Text HTML | Hi-Res PDF
Platinum Oxide Catalyzed Silylation of Aryl Halides with Triethylsilane: An Efficient Synthetic Route to Functionalized AryltriethylsilanesOrganic Letters
- Platinum Oxide Catalyzed Silylation of Aryl Halides with Triethylsilane: An Efficient Synthetic Route to Functionalized Aryltriethylsilanes
  Abdallah Hamze, Olivier Provot, Mouâd Alami, and Jean-Daniel Brion
  Organic Letters 2006 8 (5), pp 931–934
  Abstract: The first platinum-catalyzed selective silylation of aryl halides including aryl iodides and bromides having an electron-withdrawing group is described. The reaction takes place rapidly in NMP with triethylsilane as a silicon source and sodium acetate to ...
  Abstract | Full Text HTML | Hi-Res PDF

Letter

Rhodium(I)-Catalyzed Silylation of Aryl Halides with Triethoxysilane: Practical Synthetic Route to Aryltriethoxysilanes

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Synthesis of Arylsilanes via Palladium(0)-Catalyzed Silylation of Aryl Halides with Hydrosilane

Improved Synthesis of Aryltriethoxysilanes via Palladium(0)-Catalyzed Silylation of Aryl Iodides and Bromides with Triethoxysilane

Platinum Oxide Catalyzed Silylation of Aryl Halides with Triethylsilane: An Efficient Synthetic Route to Functionalized Aryltriethylsilanes

Other ACS content by these authors:

JOURNALS

BOOKS

MAGAZINE

COMMUNITIES

DIRECTORIES & DATABASES