Prev. Article Next Article Table of Contents

Letter

Carbon Monoxide Free Aminocarbonylation of Aryl and Alkenyl Iodides Using DMF as an Amide Source

Supporting Info

Kazushi Hosoi,^† Kyoko Nozaki,*^†^‡ and Tamejiro Hiyama*^†

Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan, and PRESTO, JST, Honcho, 4-1-8, Kawaguchi, Saitama 332-0012, Japan

Org. Lett., 2002, 4 (17), pp 2849–2851

DOI: 10.1021/ol026236k

Publication Date (Web): July 24, 2002

†

Kyoto University.

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

‡

JST.

, nozaki@chembio.t.u-tokyo.ac.jp

Abstract

Palladium-catalyzed coupling reaction of N,N-dimethylformamide with aryl or alkenyl halides successfully proceeded in the presence of phosphoryl chloride to afford the corresponding tertiary amides in good yields.

View: Full Text HTML | Hi-Res PDF

Tools

SciFinder Links

History

Published In Issue August 22, 2002
Received May 23, 2002

Recommend & Share

Related Content

Aminocarbonylation of Aryl Halides Using a Nickel Phosphite Catalytic SystemOrganic Letters
- Aminocarbonylation of Aryl Halides Using a Nickel Phosphite Catalytic System
  Jinhun Ju, Miso Jeong, Jeongju Moon, Hyun Min Jung, and Sunwoo Lee
  Organic Letters 2007 9 (22), pp 4615–4618
  Abstract: The nickel and phosphite catalytic system with sodium methoxide enables a very efficient aminocarbonylation reaction to be performed between aryl iodides or bromides and N,N-dimethylformamide (DMF). Phosphite ligand 1, which is very stable to air and ...
  Abstract | Full Text HTML | Hi-Res PDF
Enantiospecific Total Syntheses of Kapakahines B and FJournal of the American Chemical Society
- Enantiospecific Total Syntheses of Kapakahines B and F
  Timothy Newhouse, Chad A. Lewis and Phil S. Baran
  Journal of the American Chemical Society 2009 131 (18), pp 6360–6361
  Abstract: Gram-scale, enantiospecific total syntheses of the anti-leukemia marine natural products kapakahines B and F have been completed. Two powerfully simplifying transformations have enabled the gram-scale synthesis of this natural product family: (1) an ...
  Abstract | Full Text HTML | PDF w/ Links | Hi-Res PDF
Direct Carbamoylation of Aryl HalidesOrganic Letters
- Direct Carbamoylation of Aryl Halides
  Robert F. Cunico and Bikash C. Maity
  Organic Letters 2002 4 (24), pp 4357–4359
  Abstract: A carbamoylsilane is shown to carry out the direct carbamoylation of aryl chlorides, bromides, and iodides under catalysis by phosphinepalladium(0) complexes.
  Abstract | Full Text HTML | Hi-Res PDF

Letter

Carbon Monoxide Free Aminocarbonylation of Aryl and Alkenyl Iodides Using DMF as an Amide Source

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Aminocarbonylation of Aryl Halides Using a Nickel Phosphite Catalytic System

Enantiospecific Total Syntheses of Kapakahines B and F

Direct Carbamoylation of Aryl Halides

Other ACS content by these authors:

JOURNALS

BOOKS

MAGAZINE

COMMUNITIES

DIRECTORIES & DATABASES