Well-Defined, Air-Stable (NHC)Pd(Allyl)Cl (NHC = N-Heterocyclic Carbene) Catalysts for the Arylation of Ketones

Mihai S. Viciu, Romain F. Germaneau, and Steven P. Nolan*
Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148
Org. Lett., 2002, 4 (23), pp 4053–4056
DOI: 10.1021/ol026745m
Publication Date (Web): October 16, 2002
Copyright © 2002 American Chemical Society
*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, snolan@uno.edu

Abstract

Abstract Image

A number of palladium-N-heterocyclic carbene (NHC) complexes were found to be active catalysts for the arylation of ketones. A large number of substrates, both aryl halides and ketones, are compatible with the reaction conditions. The ketone arylation reactions are achieved with low catalyst loading in short reaction times using aryl chlorides and triflates as reactive partners.

View: Full Text HTML | Hi-Res PDF

Tools

History

  • Published In Issue November 14, 2002
  • Received August 16, 2002

Recommend & Share

Related Content

Other ACS content by these authors: