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Letter

Novel Vanadium-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones under Atmospheric Oxygen

Supporting Info

Subbarayan Velusamy and T. Punniyamurthy*

Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India

Org. Lett., 2004, 6 (2), pp 217–219

DOI: 10.1021/ol036166x

Publication Date (Web): December 18, 2003

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, tpunni@iitg.ernet.in

Abstract

Oxidation of alcohols to aldehydes and ketones has been studied in high yields using atmospheric oxygen and a catalytic amount of V₂O₅ in toluene under heating (ca. 100 °C). Secondary alcohols can be chemoselectively converted into ketones in the presence of primary hydroxy groups.

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Published In Issue January 22, 2004
Received November 5, 2003

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Letter

Novel Vanadium-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones under Atmospheric Oxygen