Selective Oxidation of Sulfides to Sulfoxides Using 30% Hydrogen Peroxide Catalyzed with a Recoverable Silica-Based Tungstate Interphase Catalyst

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Abstract

Various types of aromatic and aliphatic sulfides are selectively oxidized to sulfoxides and sulfones in good to excellent yields using 30% H₂O₂ in the presence of catalytic amounts of a novel recoverable silica-based tungstate interphase catalyst at room temperature. The catalyst can be recovered and reused for at least eight reaction cycles under the described reaction conditions without considerable loss of reactivity.

Citing Articles

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This article has been cited by 5 ACS Journal articles (5 most recent appear below).

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  A Simple and Environmentally Benign Method for Sulfoxidation of Sulfides with Hydrogen Peroxide

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  Industrial & Engineering Chemistry Research2010 49 (5), 2533-2536

  • A Simple and Environmentally Benign Method for Sulfoxidation of Sulfides with Hydrogen Peroxide

    Fenglan Liu, Zaihui Fu, Yachun Liu, Chunli Lu, Youyu Wu, Fang Xie, Zhengpei Ye, Xiaoping Zhou and Dulin Yin
    Industrial & Engineering Chemistry Research2010 49 (5), 2533-2536

    The development of a simple, efficient, and environmentally benign method for the sulfoxidation of sulfides with aqueous hydrogen peroxide is of importance for the large-scale industrial production of sulfoxides. This article first discloses that various ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Mesoporous Silica:  An Efficient Nanoreactor for Liquid−Liquid Biphase Reactions

  Renyuan Zhang, Wei Ding, Bo Tu, and Dongyuan Zhao
  Chemistry of Materials2007 19 (18), 4379-4381

  • Mesoporous Silica:  An Efficient Nanoreactor for Liquid−Liquid Biphase Reactions

    Renyuan Zhang, Wei Ding, Bo Tu, and Dongyuan Zhao
    Chemistry of Materials2007 19 (18), 4379-4381
    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  A General and Efficient Method for the Selective Synthesis of β-Hydroxy Sulfides and β-Hydroxy Sulfoxides Catalyzed by Gallium(III) Triflate

  Weike Su, Jiuxi Chen, Huayue Wu, and Can Jin
  The Journal of Organic Chemistry2007 72 (12), 4524-4527

  • A General and Efficient Method for the Selective Synthesis of β-Hydroxy Sulfides and β-Hydroxy Sulfoxides Catalyzed by Gallium(III) Triflate

    Weike Su, Jiuxi Chen, Huayue Wu, and Can Jin
    The Journal of Organic Chemistry2007 72 (12), 4524-4527

    Gallium(III) triflate-catalyzed ring opening of epoxides affords β-hydroxy sulfides with high regioselectivity and chemoselectivity in high yields (84−97%) under solvent-free conditions. Additionally, a simple, efficient, and environmentally benign one-...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  Spectroscopic and DFT Study of Tungstic Acid Peroxocomplexes

  Laura Barrio, José M. Campos-Martín, and José L. G. Fierro
  The Journal of Physical Chemistry A2007 111 (11), 2166-2171

  • Spectroscopic and DFT Study of Tungstic Acid Peroxocomplexes

    Laura Barrio, José M. Campos-Martín, and José L. G. Fierro
    The Journal of Physical Chemistry A2007 111 (11), 2166-2171

    The catalytic system formed by tungstic acid and its complexes with H2O2 and phenylphosphonic acid has been analyzed from the experimental and theoretical points of view. Previous structural studies by XRD proved the validity of the DFT proposed models ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links
• 

  WO₃ Nanoparticles on MCM-48 as a Highly Selective and Versatile Heterogeneous Catalyst for the Oxidation of Olefins, Sulfides, and Cyclic Ketones

  Dong Hyun Koo, Min Kim, and Sukbok Chang
  Organic Letters2005 7 (22), 5015-5018

  • WO₃ Nanoparticles on MCM-48 as a Highly Selective and Versatile Heterogeneous Catalyst for the Oxidation of Olefins, Sulfides, and Cyclic Ketones

    Dong Hyun Koo, Min Kim, and Sukbok Chang
    Organic Letters2005 7 (22), 5015-5018

    It is shown that nanosized WO3 particles supported on MCM-48 work as a highly efficient and selective heterogeneous catalyst for the oxidation of olefins, sulfides, and cyclic ketones using hydrogen peroxide or peracetic acid. The catalytic activity of ...

    Abstract | Full Text HTML | Hi-Res PDF | PDF w/ Links

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