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Letter

Versatile Dehydrogenative Alcohol Silylation Catalyzed by Cu(I)−Phosphine Complex

Supporting Info

Hajime Ito,* Akiko Watanabe, and Masaya Sawamura*;

Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan, and PRESTO, Japan Science and Technology Agency

Org. Lett., 2005, 7 (9), pp 1869–1871

DOI: 10.1021/ol050559+

Publication Date (Web): April 7, 2005

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, hajito@sci.hokudai.ac.jp, ; , sawamura@sci.hokudai.ac.jp

Abstract

Cu(I) complexes of xanthane-based diphosphines were versatile catalysts for dehydrogenative alcohol silylation, exhibiting high activity and broad substrate scope. Highly selective silylation of 1-decanol over 2-decanol is possible even with a silylating reagent of small steric demand such as HSiMe₂Ph or HSiEt₃.

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Published In Issue April 28, 2005
Received March 15, 2005

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Letter

Versatile Dehydrogenative Alcohol Silylation Catalyzed by Cu(I)−Phosphine Complex

Abstract

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Recommend & Share

Related Content

Gold(I)−Phosphine Catalyst for the Highly Chemoselective Dehydrogenative Silylation of Alcohols

Enantioselective Addition of Terminal Alkynes to Aldehydes Catalyzed by a Cu(I)−TRAP Complex

Copper-Catalyzed γ-Selective and Stereospecific Substitution Reaction of Allylic Carbonates with Diboron: Efficient Route to Chiral Allylboron Compounds

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