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Letter

Copper(II)-Catalyzed Aerobic Oxidation of Primary Alcohols to Aldehydes in Ionic Liquid [bmpy]PF₆

Supporting Info

Nan Jiang and Arthur J. Ragauskas*

Department of Chemistry, Georgia Institute of Technology, Atlanta, Georgia 30332

Org. Lett., 2005, 7 (17), pp 3689–3692

DOI: 10.1021/ol051293+

Publication Date (Web): July 22, 2005

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, arthur.ragauskas@chemistry.gatech.edu

Abstract

A room-temperature aerobic oxidation of primary alcohols to aldehydes catalyzed by the three-component system acetamido-TEMPO/Cu(ClO₄)₂/DMAP in the ionic liquid [bmpy]PF₆ has been developed, and the catalysts can be recycled and reused for five runs without any significant loss of catalytic activity.

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Published In Issue August 18, 2005
Received June 2, 2005

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Letter

Copper(II)-Catalyzed Aerobic Oxidation of Primary Alcohols to Aldehydes in Ionic Liquid [bmpy]PF₆