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Letter

Palladium-Catalyzed Addition of Arylboronic Acids to Aldehydes

Supporting Info

Tetsuya Yamamoto, Tetsuo Ohta,* and Yoshihiko Ito

Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0394, Japan

Org. Lett., 2005, 7 (19), pp 4153–4155

DOI: 10.1021/ol051501y

Publication Date (Web): August 18, 2005

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, tota@mail.doshisha.ac.jp

Abstract

Arylboronic acids react with aldehydes in the presence of a base and a catalytic amount of a palladium(0) complex with chloroform, affording the corresponding secondary alcohols in good yields. General palladium complexes have no catalytic activity without chloroform. Chloroform is essential for this reaction, and palladium complex that was prepared from Pd(PPh₃)₄ with CHCl₃ showed good catalytic acitivty as well.

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Published In Issue September 15, 2005
Received June 27, 2005

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Letter

Palladium-Catalyzed Addition of Arylboronic Acids to Aldehydes

Abstract

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SciFinder Links

History

Recommend & Share

Related Content

Cationic Pd(II)/Bipyridine-Catalyzed Addition of Arylboronic Acids to Arylaldehydes. One-Pot Synthesis of Unsymmetrical Triarylmethanes

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The Palladium-Catalyzed Addition of Aryl- and Heteroarylboronic Acids to Aldehydes

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