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Letter

Enhanced Small-Molecule Assembly through Directional Intramolecular Forces

Supporting Info

Andrew J. Lampkins, Osama Abdul-Rahim, Hengfeng Li, and Ronald K. Castellano*

Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, Florida 32611-7200

Org. Lett., 2005, 7 (20), pp 4471–4474

DOI: 10.1021/ol051768x

Publication Date (Web): September 3, 2005

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, castellano@chem.ufl.edu

Abstract

Directional intramolecular interactions play a critical role in the self-assembly of donor-σ-acceptor molecules in solution. Amide functions on the periphery of the tricyclic core stabilize a C₃-symmetric monomer conformation by intramolecular hydrogen bonding and dipole−dipole interactions. The molecules are effective organogelators and show long-range ordering in the bulk.

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Published In Issue September 29, 2005
Received July 26, 2005

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Letter

Enhanced Small-Molecule Assembly through Directional Intramolecular Forces

Abstract

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SciFinder Links

History

Recommend & Share

Related Content

Synthesis and Self-Assembly of Functionalized Donor−σ−Acceptor Molecules

Examination of the Structural Features That Favor the Columnar Self-Assembly of Bis-urea Macrocycles

Metal Complexes of Cinchonine as Chiral Building Blocks: A Strategy for the Construction of Nanotubular Architectures and Helical Coordination Polymers

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