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Letter

Microwave-Enhanced Palladium-Catalyzed Cross-Coupling Reactions of Potassium Vinyltrifluoroborates and Allyl Acetates: A New Route to 1,4-Pentadienes

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George W. Kabalka*^† and Mohammad Al-Masum^‡

Departments of Chemistry and Radiology, The University of Tennessee, Knoxville, Tennessee 37996-1600, and Department of Chemistry, Tennessee State University, Nashville, Tennessee 37209

Org. Lett., 2006, 8 (1), pp 11–13

DOI: 10.1021/ol051955v

Publication Date (Web): December 3, 2005

To whom all corresspondence should be addressed. Ph: (865)974-3260. Fax: (865)974-2997.

†

The University of Tennessee.

‡

Tennessee State University.

, kabalka@utk.edu

Abstract

A novel and straightforward microwave synthesis of 1,4-pentadienes has been developed involving the cross-coupling of potassium vinyltrifluoroborates and allyl acetates in the presence of a palladium catalyst.

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Published In Issue January 05, 2006
Received August 12, 2005

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Letter

Microwave-Enhanced Palladium-Catalyzed Cross-Coupling Reactions of Potassium Vinyltrifluoroborates and Allyl Acetates: A New Route to 1,4-Pentadienes

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Iron-Catalyzed 1,4-Addition of α-Olefins to Dienes

Chemoselectivity: The Mother of Invention in Total Synthesis

Catalytic Carbon−Carbon σ Bond Activation: An Intramolecular Carbo-Acylation Reaction with Acylquinolines

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