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Letter

cis-Dihydroxylation of Unsaturated Potassium Alkyl- and Aryltrifluoroborates

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Gary A. Molander* and Ruth Figueroa

Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323

Org. Lett., 2006, 8 (1), pp 75–78

DOI: 10.1021/ol052549e

Publication Date (Web): December 3, 2005

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, gmolandr@sas.upenn.edu

Abstract

The cis-dihydroxylation of olefin-containing potassium alkyl- and aryltrifluoroborates proceeds readily in moderate to excellent yields. The resulting diols are efficient coupling partners in Suzuki−Miyaura-type reactions with both alkenyl and aryl bromides.

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Published In Issue January 05, 2006
Received October 20, 2005

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Letter

cis-Dihydroxylation of Unsaturated Potassium Alkyl- and Aryltrifluoroborates

Abstract

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SciFinder Links

History

Recommend & Share

Related Content

One-Pot Synthesis of Trisubstituted Conjugated Dienes via Sequential Suzuki−Miyaura Cross-Coupling with Alkenyl- and Alkyltrifluoroborates

Suzuki Cross-Coupling Reactions of Potassium Alkenyltrifluoroborates

B-Alkyl Suzuki−Miyaura Cross-Coupling Reactions with Air-Stable Potassium Alkyltrifluoroborates

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