Prev. Article Next Article Table of Contents

Letter

Gold(I)-Catalyzed Oxidative Cleavage of a C−C Double Bond in Water

Supporting Info

Dong Xing,^† Bingtao Guan,^‡ Guixin Cai,^‡ Zhao Fang,^‡ Liping Yang,^† and Zhangjie Shi*^‡

Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China, State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China, and Department of Chemistry, East China Normal University, Shanghai 200062, China

Org. Lett., 2006, 8 (4), pp 693–696

DOI: 10.1021/ol052830t

Publication Date (Web): January 19, 2006

†

East China Normal University.

‡

Peking University.

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, zshi@pku.edu.cn

Abstract

Oxidative cleavage of the CC bond to afford ketone or aldehyde products with tert-butyl hydrogenperoxide (TBHP) as the oxidant can be catalyzed by AuCl with neocuproine (1) in water.

View: Full Text HTML | Hi-Res PDF

Tools

SciFinder Links

History

Published In Issue February 16, 2006
Received November 23, 2005

Recommend & Share

Related Content

Indirect ortho Functionalization of Substituted Toluenes through ortho Olefination of N,N-Dimethylbenzylamines Tuned by the Acidity of Reaction ConditionsJournal of the American Chemical Society
- Indirect ortho Functionalization of Substituted Toluenes through ortho Olefination of N,N-Dimethylbenzylamines Tuned by the Acidity of Reaction Conditions
  Guixin Cai, Ye Fu, Yizhou Li, Xiaobing Wan, and Zhangjie Shi
  Journal of the American Chemical Society 2007 129 (24), pp 7666–7673
  Abstract: Highly regioselective olefination of substituted N,N-dimethylbenzylamines was developed by tuning the acidity of reaction conditions based on analysis of their features. The ortho-functionalized N,N-dimethylbenzylamines were further transformed into 3-(2‘-...
  Abstract | Full Text HTML | Hi-Res PDF
Highly Selective Aerobic Oxidation of Alcohol Catalyzed by a Gold(I) Complex with an Anionic LigandJournal of the American Chemical Society
- Highly Selective Aerobic Oxidation of Alcohol Catalyzed by a Gold(I) Complex with an Anionic Ligand
  Bingtao Guan, Dong Xing, Guixing Cai, Xiaobin Wan, Nan Yu, Zhao Fang, Liping Yang, and Zhangjie Shi
  Journal of the American Chemical Society 2005 127 (51), pp 18004–18005
  Abstract: Highly selective aerobic oxidation of alcohols to carbonyl compounds was catalyzed by a gold(I) complex with an anionic ligand in solution.
  Abstract | Full Text HTML | Hi-Res PDF
Highly Selective C−H Functionalization/Halogenation of Acetanilide Highly Selective C−H Functionalization/Halogenation of AcetanilideJournal of the American Chemical Society
- Highly Selective C−H Functionalization/Halogenation of Acetanilide Highly Selective C−H Functionalization/Halogenation of Acetanilide
  Xiaobing Wan, Zhongxun Ma, Bijie Li, Keya Zhang, Shaokui Cao, Shiwei Zhang, and Zhangjie Shi
  Journal of the American Chemical Society 2006 128 (23), pp 7416–7417
  Abstract: Highly regioselective C−H functionalization/halogenation of acetanilides to produce ortho-haloacetanilides was catalyzed by Pd(OAc)₂ and Cu(OAc)₂ with CuX₂ as the halogen source.
  Abstract | Full Text HTML | Hi-Res PDF

Letter

Gold(I)-Catalyzed Oxidative Cleavage of a C−C Double Bond in Water

Abstract

Tools

SciFinder Links

History

Recommend & Share

Related Content

Indirect ortho Functionalization of Substituted Toluenes through ortho Olefination of N,N-Dimethylbenzylamines Tuned by the Acidity of Reaction Conditions

Highly Selective Aerobic Oxidation of Alcohol Catalyzed by a Gold(I) Complex with an Anionic Ligand

Highly Selective C−H Functionalization/Halogenation of Acetanilide Highly Selective C−H Functionalization/Halogenation of Acetanilide

Other ACS content by these authors:

JOURNALS

BOOKS

MAGAZINE

COMMUNITIES

DIRECTORIES & DATABASES