Novel Trans-Spanned Palladium Complexes as Efficient Catalysts in Mild and Amine-Free Cyanation of Aryl Bromides under Air

Olga Grossman and Dmitri Gelman*
Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel
Org. Lett., 2006, 8 (6), pp 1189–1191
DOI: 10.1021/ol0601038
Publication Date (Web): February 22, 2006
Copyright © 2006 American Chemical Society
*

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, dgelman@chem.ch.huji.ac.il

Abstract

Abstract Image

The use of a novel trans-spanned palladium complex as an efficient and selective catalyst in the cyanation of aryl halides is described. The suggested reaction conditions are mild, exhibit good scope of substrates, and circumvent the need for an inert atmosphere and amine co-ligands.

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History

  • Published In Issue March 16, 2006
  • Received January 13, 2006

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