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Letter

Enantioselective Rh-Catalyzed Arylation of N-Tosylarylimines with Arylboronic Acids

Supporting Info

Hai-Feng Duan, Yi-Xia Jia, Li-Xin Wang, and Qi-Lin Zhou*

State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China

Org. Lett., 2006, 8 (12), pp 2567–2569

DOI: 10.1021/ol060755w

Publication Date (Web): May 13, 2006

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, qlzhou@nankai.edu.cn

Abstract

The asymmetric arylation of N-tosylarylimines with arylboronic acids was realized by using rhodium/(S)-ShiP as catalyst. The reaction proceeded in aqueous toluene to give diarylmethylamines in good yields with up to 96% ee.

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Published In Issue June 08, 2006
Received March 28, 2006

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Letter

Enantioselective Rh-Catalyzed Arylation of N-Tosylarylimines with Arylboronic Acids