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Letter

Cobalt-Catalyzed Aryl−Sulfur Bond Formation

Supporting Info

Ying-Chieh Wong, Thiruvellore Thatai Jayanth, and Chien-Hong Cheng*

Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan

Org. Lett., 2006, 8 (24), pp 5613–5616

DOI: 10.1021/ol062344l

Publication Date (Web): November 3, 2006

In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

, chcheng@mx.nthu.edu.tw

Abstract

A new cobalt-catalyzed coupling of aryl halides with thiophenols and alkanethiols is reported. A variety of aryl sulfides can be prepared in excellent yields under mild reaction conditions using 1−2 mol % of CoI₂(dppe) and Zn. This new cobalt-catalyzed coupling represents an interesting addition to previously known methods to synthesize thioethers.

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Published In Issue November 23, 2006
Received September 23, 2006

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Letter

Cobalt-Catalyzed Aryl−Sulfur Bond Formation

Abstract

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SciFinder Links

History

Recommend & Share

Related Content

A General Method for the Formation of Aryl−Sulfur Bonds Using Copper(I) Catalysts

A General, Efficient, and Inexpensive Catalyst System for the Coupling of Aryl Iodides and Thiols

A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols A General and Long-Lived Catalyst for the Palladium-Catalyzed Coupling of Aryl Halides with Thiols

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